Preparation and crystal structure of bis(pi-pentamethylcyclopentadienyl) (2-methylene)(3-diphenylmethylene)oxatitanacyclobutane Cp*Ti-2-OC(=CPh2)-C=CH2

被引：9
|
作者：
Beckhaus, R
Strauss, I
Wagner, T
机构：
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 04期
关键词：
titanium; vinylidene complexes; cycloaddition reaction; oxatitanacyclobutanes; crystal structure;
D O I：
10.1002/zaac.199762301104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex 5 was synthesized by a [2 + 2]-cycloaddition reaction of diphenylketene and the titanaallene fragment [Cp-2*Ti=C=CH2] (3). Complex 5 was characterized using H-1 and C-13 NMR spectra and by X-ray structure analysis, respectively.
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收藏
页码：654 / 658
页数：5
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