Preparation and crystal structure of bis(pi-pentamethylcyclopentadienyl) (2-methylene)(3-diphenylmethylene)oxatitanacyclobutane Cp*Ti-2-OC(=CPh2)-C=CH2

被引：9

作者：

Beckhaus, R

Strauss, I

Wagner, T

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 04期

关键词：

titanium; vinylidene complexes; cycloaddition reaction; oxatitanacyclobutanes; crystal structure;

D O I：

10.1002/zaac.199762301104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex 5 was synthesized by a [2 + 2]-cycloaddition reaction of diphenylketene and the titanaallene fragment [Cp-2*Ti=C=CH2] (3). Complex 5 was characterized using H-1 and C-13 NMR spectra and by X-ray structure analysis, respectively.

引用

页码：654 / 658

页数：5

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