Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2 under Ambient Conditions

被引：526

作者：

Gao, Wen-Yang ^{[1
]}

Chen, Yao ^{[1
]}

Niu, Youhong ^{[1
]}

Williams, Kia ^{[1
]}

Cash, Lindsay ^{[1
]}

Perez, Pastor J. ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Cai, Jianfeng ^{[1
]}

Chen, Yu-Sheng ^{[2
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, 4202 E Fowler Ave, Tampa, FL 33620 USA

[2] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 10期

基金：

美国国家科学基金会;

关键词：

carbon dioxide; chemical fixation; crystal engineering; metal-organic frameworks; nbo topology; CARBON-DIOXIDE CAPTURE; HIGH H-2 ADSORPTION; CATALYTIC-ACTIVITY; CYCLIC CARBONATES; POROUS MATERIALS; PORE-SIZE; CYCLOADDITION; CONVERSION; OXIDE; EPOXIDES;

D O I：

10.1002/anie.201309778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N,N,N-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu-2(Cu-tactmb)(H2O)(3)(NO3)(2)]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1atm pressure.

引用

页码：2615 / 2619

页数：5

共 83 条

[31] Size-selective lewis acid catalysis in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].

Horike, Satoshi ;

Dinca, Mircea ;

Tamaki, Kentaro ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (18) :5854-+

[32] Unconventional, Highly Selective CO2 Adsorption in Zeolite SSZ-13 [J].

Hudson, Matthew R. ;

Queen, Wendy L. ;

Mason, Jarad A. ;

Fickel, Dustin W. ;

Lobo, Raul F. ;

Brown, Craig M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (04) :1970-1973

[33] Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst [J].

Jiang, Tao ;

Ma, Xiumin ;

Zhou, Yinxi ;

Liang, Shuguang ;

Zhang, Jicheng ;

Han, Buxing .

GREEN CHEMISTRY, 2008, 10 (04) :465-469

[34]

Johnson J, 2004, CHEM ENG NEWS, V82, P36, DOI 10.1021/cen-v082n038.p036

[35] CO2 cycloaddition of styrene oxide over MOF catalysts [J].

Kim, Jun ;

Kim, Se-Na ;

Jang, Hoi-Gu ;

Seo, Gon ;

Ahn, Wha-Seung .

APPLIED CATALYSIS A-GENERAL, 2013, 453 :175-180

[36] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[37]

Kitagawa S., 2004, ANGEW CHEM-GER EDIT, V116, P2388, DOI [DOI 10.1021/ic010326o, DOI 10.1002/ANIE.200300610]

[38]

Lee Y-G., 2008, ANGEW CHEM, V120, P7855

[39] A comparison of the H2 sorption capacities of isostructural metal-organic frameworks with and without accessible metal sites:: [{Zn2(abtc)(dMf)2}3] and [{Cu2(abtc)(dMf)2}3] versus [{Cu2(abtc)}3] [J].

Lee, Yong-Gon ;

Moon, Hoi Ri ;

Cheon, Young Eun ;

Suh, Myunghyun Paik .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (40) :7741-7745

[40] Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks [J].

Li, Jian-Rong ;

Ma, Yuguang ;

McCarthy, M. Colin ;

Sculley, Julian ;

Yu, Jiamei ;

Jeong, Hae-Kwon ;

Balbuena, Perla B. ;

Zhou, Hong-Cai .

COORDINATION CHEMISTRY REVIEWS, 2011, 255 (15-16) :1791-1823

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