Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2 under Ambient Conditions

被引：526

作者：

Gao, Wen-Yang ^{[1
]}

Chen, Yao ^{[1
]}

Niu, Youhong ^{[1
]}

Williams, Kia ^{[1
]}

Cash, Lindsay ^{[1
]}

Perez, Pastor J. ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Cai, Jianfeng ^{[1
]}

Chen, Yu-Sheng ^{[2
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, 4202 E Fowler Ave, Tampa, FL 33620 USA

[2] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 10期

基金：

美国国家科学基金会;

关键词：

carbon dioxide; chemical fixation; crystal engineering; metal-organic frameworks; nbo topology; CARBON-DIOXIDE CAPTURE; HIGH H-2 ADSORPTION; CATALYTIC-ACTIVITY; CYCLIC CARBONATES; POROUS MATERIALS; PORE-SIZE; CYCLOADDITION; CONVERSION; OXIDE; EPOXIDES;

D O I：

10.1002/anie.201309778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N,N,N-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu-2(Cu-tactmb)(H2O)(3)(NO3)(2)]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1atm pressure.

引用

页码：2615 / 2619

页数：5

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