Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2 under Ambient Conditions

被引：528

作者：

Gao, Wen-Yang ^{[1
]}

Chen, Yao ^{[1
]}

Niu, Youhong ^{[1
]}

Williams, Kia ^{[1
]}

Cash, Lindsay ^{[1
]}

Perez, Pastor J. ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Cai, Jianfeng ^{[1
]}

Chen, Yu-Sheng ^{[2
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, 4202 E Fowler Ave, Tampa, FL 33620 USA

[2] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 10期

基金：

美国国家科学基金会;

关键词：

carbon dioxide; chemical fixation; crystal engineering; metal-organic frameworks; nbo topology; CARBON-DIOXIDE CAPTURE; HIGH H-2 ADSORPTION; CATALYTIC-ACTIVITY; CYCLIC CARBONATES; POROUS MATERIALS; PORE-SIZE; CYCLOADDITION; CONVERSION; OXIDE; EPOXIDES;

D O I：

10.1002/anie.201309778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N,N,N-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu-2(Cu-tactmb)(H2O)(3)(NO3)(2)]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1atm pressure.

引用

页码：2615 / 2619

页数：5

共 83 条

[1]

[Anonymous], 2010, ANGEW CHEM

[2]

[Anonymous], 2008, ANGEW CHEM-GER EDIT

[3]

[Anonymous], 2013, ANGEW CHEM-GER EDIT

[4]

[Anonymous], 2012, Angew. Chemie, DOI DOI 10.1002/ANGE.201202176

[5]

[Anonymous], ANGEW CHEM, DOI DOI 10.1002/ange.200462787

[6] The contribution of the utilization option to reducing the CO2 atmospheric loading:: research needed to overcome existing barriers for a full exploitation of the potential of the CO2 use [J].

Aresta, M ;

Dibenedetto, A .

CATALYSIS TODAY, 2004, 98 (04) :455-462

[7] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[8] Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability [J].

Biswal, Bishnu P. ;

Panda, Tamas ;

Banerjee, Rahul .

CHEMICAL COMMUNICATIONS, 2012, 48 (97) :11868-11870

[9] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

[10] Size-Selective Biocatalysis of Myoglobin Immobilized into a Mesoporous Metal-Organic Framework with Hierarchical Pore Sizes [J].

Chen, Yao ;

Lykourinou, Vasiliki ;

Tran Hoang ;

Ming, Li-June ;

Ma, Shengqian .

INORGANIC CHEMISTRY, 2012, 51 (17) :9156-9158

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