A General Catalytic Methylation of Amines Using Carbon Dioxide

被引：227
作者：
Li, Yuehui [1 ]
Fang, Xianjie [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构：
[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 36期
关键词：
carbon dioxide; methylation; reduction; ruthenium; silanes; DEFINED IRON CATALYST; HOMOGENEOUS HYDROGENATION; IRIDIUM CATALYST; N-ALKYLATION; FORMIC-ACID; REDUCTION; CO2; HYDROSILYLATION; DERIVATIVES; COMPLEXES;
D O I：
10.1002/anie.201301349
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Putting CO2 to work: Carbon dioxide is shown to be a general and selective methylating reagent for secondary and primary, aromatic and aliphatic amines under reductive conditions. A variety of tertiary amines are obtained from CO2 and commercially available silanes in high yields with good tolerance to nitrile, olefin, ether, ester, and hydroxy groups. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9568 / 9571
页数：4
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