Influence of bismuth on the magnetic & electrical properties of La2MnNiO6

被引:9
作者
Nautiyal, Pranjal [1 ,2 ]
Seikh, Md. Motin [3 ]
Pralong, V. [4 ]
Kundu, Asish K. [1 ]
机构
[1] Indian Inst Informat Technol Design & Mfg, Discipline Phys, Jabalpur 482005, India
[2] Indian Inst Informat Technol Design & Mfg, Discipline Mech Engn, Jabalpur 482005, India
[3] Visva Bharati Univ, Dept Chem, Santini Ketan 731235, W Bengal, India
[4] ENSICAEN UMR6508, Lab CRISMAT, F-14050 Caen 4, France
关键词
Doping; Magnetism; Multiferroic; Ferromagnetic;
D O I
10.1016/j.jmmm.2013.07.062
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, we report the ambient pressure and low temperature synthesis of ordered perovskite La2-xBixMn1+yNi1-yO6 with high bismuth content. Keeping y=0, we are able to substitute La by Bi up to x=0.4 i.e. 20% of La. However, 50% La could be replaced by Bi for y=0.5 without any impurity phases. Interestingly, these compounds remain ferromagnetic with the Curie temperature T-C of 255 and 75 K for La1.6Bi0.4MnNiO6 and LaBiMn1.5Ni0.5O6 compositions, respectively. Moreover, these Bi-substituted phases become more conducting, three order of magnitude higher, at room temperature compared to the parent La2MnNiO6 phase. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:111 / 115
页数:5
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