Assessing the adsorption selectivity of linker functionalized, moisture-stable metal-organic framework thin films by means of an environment-controlled quartz crystal microbalance

被引：46

作者：

Betard, Angelique ^{[1
]}

Wannapaiboon, Suttipong ^{[1
]}

Fischer, Roland A. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 85期

关键词：

DEPOSITION; MOF-5;

D O I：

10.1039/c2cc34608g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stepwise thin film deposition of the robust, hydrophobic [Zn4O(dmcapz)(3)](n) (dmcapz = 3,5-dimethyl-4-carboxy-pyrazolato) is reported. The adsorption of small organic probe molecules, including alkanols, toluene, aniline and xylenes, was monitored by an environment-controlled quartz crystal microbalance setup. The adsorption selectivity was tuned by introducing alkyl side chains in the dmcapz linker.

引用

收藏

页码：10493 / 10495

页数：3

相关论文

共 16 条

[1] Stress-induced Chemical Detection Using Flexible Metal-Organic Frameworks [J].

Allendorf, Mark D. ;

Houk, Ronald J. T. ;

Andruszkiewicz, Leanne ;

Talin, A. Alec ;

Pikarsky, Joel ;

Choudhury, Arnab ;

Gall, Kenneth A. ;

Hesketh, Peter J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (44) :14404-+

[2] Metal-Organic Framework Thin Films: From Fundamentals to Applications [J].

Betard, Angelique ;

Fischer, Roland A. .

CHEMICAL REVIEWS, 2012, 112 (02) :1055-1083

[3] Fabrication of a CO2-selective membrane by stepwise liquid-phase deposition of an alkylether functionalized pillared-layered metal-organic framework [Cu2L2P]n on a macroporous support [J].

Betard, Angelique ;

Bux, Helge ;

Henke, Sebastian ;

Zacher, Denise ;

Caro, Juergen ;

Fischer, Roland A. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 150 (01) :76-82

[4] Metal-Organic Framework Thin Film for Enhanced Localized Surface Plasmon Resonance Gas Sensing [J].

Kreno, Lauren E. ;

Hupp, Joseph T. ;

Van Duyne, Richard P. .

ANALYTICAL CHEMISTRY, 2010, 82 (19) :8042-8046

[5] Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].

Li, H ;

Eddaoudi, M ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 1999, 402 (6759) :276-279

[6] Enantiopure Metal-Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption [J].

Liu, Bo ;

Shekhah, Osama ;

Arslan, Hasan K. ;

Liu, Jinxuan ;

Woell, Christof ;

Fischer, Roland A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (03) :807-810

[7] Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces [J].

Meilikhov, Mikhail ;

Yusenko, Kirill ;

Schollmeyer, Eckhardt ;

Mayer, Christian ;

Buschmann, Hans-Juergen ;

Fischer, Roland A. .

DALTON TRANSACTIONS, 2011, 40 (18) :4838-4841

[8] Capture of Nerve Agents and Mustard Gas Analogues by Hydrophobic Robust MOF-5 Type Metal-Organic Frameworks [J].

Montoro, Carmen ;

Linares, Fatima ;

Quartapelle Procopio, Elsa ;

Senkovska, Irena ;

Kaskel, Stefan ;

Galli, Simona ;

Masciocchi, Norberto ;

Barea, Elisa ;

Navarro, Jorge A. R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (31) :11888-11891

[9] High-Separation Performance of Chromatographic Capillaries Coated with MOF-5 by the Controlled SBU Approach [J].

Muench, Alexander S. ;

Seidel, Juergen ;

Obst, Anja ;

Weber, Edwin ;

Mertens, Florian O. R. L. .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (39) :10958-10964

[10] A route to the synthesis of trivalent transition-metal porous carboxylates with trimeric secondary building units [J].

Serre, C ;

Millange, F ;

Surblé, S ;

Férey, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6286-6289