Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

被引：110
作者：
Igawa, Kazunobu [1 ]
Yoshihiro, Daisuke [2 ]
Ichikawa, Nobumasa [2 ]
Kokan, Naoto [3 ]
Tomooka, Katsuhiko [1 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan
[2] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Fukuoka 8168580, Japan
[3] Tokyo Inst Technol, Dept Appl Chem, Tokyo, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 51期
关键词：
asymmetric synthesis; enantioselectivity; hydrosilylation; ozone; silanes; ASYMMETRIC-SYNTHESIS; RACEMIC ACETYL(TERT-BUTYL)METHYLPHENYLSILANE; EFFICIENT APPROACH; SILICON; DERIVATIVES; HYDROSILYLATION; SILANES; COMPLEXES; KETONES; ALKYNES;
D O I：
10.1002/anie.201207361
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12745 / 12748
页数：4
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