Controlled Phase Separation in Flexible Polyurethane Foams with Diethanolamine Cross-Linker for Improved Sound Absorption Efficiency

被引:28
作者
Kim, Seok Kyeong [1 ]
Sung, Giwook [1 ]
Gwon, Jae Gyoung [1 ]
Kim, Jung Hyeun [1 ]
机构
[1] Univ Seoul, Dept Chem Engineenng, 163 Seoulsiripdae Ro, Seoul 02504, South Korea
关键词
Polyurethane foams; Catalysts; Diethanolamine (DEA); Sound absorption coefficient; MORPHOLOGY DEVELOPMENT; BEHAVIOR; DEOA;
D O I
10.1007/s40684-016-0046-y
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
For comfortable driving conditions, flexible polyurethane (PU) foams are used for sound absorbers in noise, vibration, harshness (NVH) systems. The cellular structures of PU foams are important to improve the sound absorption efficiency, and the cell morphology is strongly dependent the use of experimental ingredients such as catalysts and cross-linking agents. Uniform cavity size distribution is achieved by controlling the catalyst ratio between gelling and blowing catalysts, and the optimum catalyst ratio (9:1) is used with a diethanolamine (DEA) cross-linker for improved sound absorption efficiency. DEA affects pore morphology by preventing phase separation in PU matrix, and the number of open pores reduces with increasing DEA contents. Sound absorption coefficient shows the highest at 9:1 catalyst ratio and 0.9 g DEA usage in the flexible PU foams under disturbed phase separation conditions.
引用
收藏
页码:367 / 373
页数:7
相关论文
共 27 条
[21]   Effect of foam density on the properties of water blown rigid polyurethane foam [J].
Thirumal, M. ;
Khastgir, Dipak ;
Singha, Nikhil K. ;
Manjunath, B. S. ;
Naik, Y. P. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 108 (03) :1810-1817
[22]   Flexible polyurethane foams based on 100% renewably sourced polyols [J].
Ugarte, L. ;
Saralegi, A. ;
Fernandez, R. ;
Martin, L. ;
Corcuera, M. A. ;
Eceiza, A. .
INDUSTRIAL CROPS AND PRODUCTS, 2014, 62 :545-551
[23]   Enhanced acoustic damping in flexible polyurethane foams filled with carbon nanotubes [J].
Verdejo, R. ;
Staempfli, R. ;
Alvarez-Lainez, M. ;
Mourad, S. ;
Rodriguez-Perez, M. A. ;
Bruehwiler, P. A. ;
Shaffer, M. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (10) :1564-1569
[24]   Influences of Rice Hull in Polyurethane Foam on Its Sound Absorption Characteristics [J].
Wang, Yonghua ;
Zhang, Chengchun ;
Ren, Luquan ;
Ichchou, Mohamed ;
Galland, Marie-Annick ;
Bareille, Olivier .
POLYMER COMPOSITES, 2013, 34 (11) :1847-1855
[25]   Microphase separation, stress relaxation, and creep behavior of polyurethane nanocomposites [J].
Xia, Hesheng ;
Song, Mo ;
Zhang, Zhongyi ;
Richardson, Mel .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (05) :2992-3002
[26]   Correlation between the acoustic and porous cell morphology of polyurethane foam: Effect of interconnected porosity [J].
Zhang, Chunhua ;
Li, Junqing ;
Hu, Zhen ;
Zhu, Fenglei ;
Huang, Yudong .
MATERIALS & DESIGN, 2012, 41 :319-325
[27]   Role of silicone surfactant in flexible polyurethane foam [J].
Zhang, XD ;
Macosko, CW ;
Davis, HT ;
Nikolov, AD ;
Wasan, DT .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 215 (02) :270-279