Bis(1-tert-butyl-1H-imidazole-κN3)dichloridocobalt(II)

被引：1

作者：

Herdtweck, Eberhardt ^{[1
]}

Zeller, Alexander ^{[1
]}

Strassner, Thomas ^{[2
]}

机构：

[1] Tech Univ Munich, Dept Chem, Lehrstuhl Anorgan Chem, D-85747 Garching, Germany

[2] Tech Univ Dresden, Lehrstuhl Phys Organ Chem, D-01069 Dresden, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2012年 / 68卷

关键词：

N-HETEROCYCLIC CARBENES; COMPLEXES;

D O I：

10.1107/S0108270112020884

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the crystal structure of the title compound, [CoCl2(C7H12N2)2], molecular units are formed by coordination of the unsubstituted N atoms of two tert-butyl-substituted imidazole molecules and two chloride ligands, which distinguishes the complex from structures of imidazolium-based dications with tetrachloridocobaltate dianions. There are two crystallographically independent molecules in the asymmetric unit, related by a noncrystallographic inversion centre.

引用

页码：M166 / M168

页数：3

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