A Highly Luminescent Hexanuclear Molybdenum Cluster - A Promising Candidate toward Photoactive Materials

被引：135

作者：

Kirakci, Kaplan ^{[1
]}

Kubat, Pavel ^{[2
]}

Dusek, Michal ^{[3
]}

Fejfarova, Karla ^{[3
]}

Sicha, Vaclav ^{[1
]}

Mosinger, Jiri ^{[1
,4
]}

Lang, Kamil ^{[1
]}

机构：

[1] AS CR, Inst Inorgan Chem, Vvi, Rez 25068, Czech Republic

[2] ASCR, J Heyrovsky Inst Phys Chem, Vvi, Prague 18223, Czech Republic

[3] AS CR, Inst Phys, Vvi, Prague 18221 8, Czech Republic

[4] Charles Univ Prague, Fac Sci, Prague 12843 2, Czech Republic

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 19期

关键词：

Cluster compounds; Luminescence; Molybdenum; Organic-inorganic hybrid composites; Singlet oxygen; SINGLET OXYGEN; PHOTOPHYSICAL PROPERTIES; COMPLEX; PLATINUM(II); NANOFABRICS; STATE;

D O I：

10.1002/ejic.201200402

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Mo-6 cluster complex and its silica and polyurethane composites have been synthesized and characterized. These materials are highly luminescent with emission above 650 nm, produce singlet oxygen with high efficiency, are photostable, and can be excited up to 580 nm. These properties are desirable for the construction of luminescent probes of oxygen, photoactive materials for oxidation reactions with easily separable active carriers, and bactericidal textile surfaces upon daylight irradiation.

引用

页码：3107 / 3111

页数：5

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