Rotationally resolved differential scattering cross sections for the reaction F+para-H2 (v=0,j=0)→HF(v′=2,3,j′)+H

被引:34
作者
Baer, M
Faubel, M
Martínez-Haya, B
Rusin, L
Tappe, U
Toennies, JP
机构
[1] Max Planck Inst Stromungsforsch, D-37073 Gottingen, Germany
[2] SOREQ NRC, IL-81800 Yavne, Israel
[3] Russian Acad Sci, Inst Energy Problems Chem Phys, Moscow 117829, Russia
关键词
D O I
10.1063/1.478955
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Time-of-flight spectra of HF products in the v' = 2 vibrational state from reactive scattering of F atoms from para-H-2 exhibit at least four smaller peaks which are assigned to the rotational states j' = 7, 8, 9, and 10. The center-of-mass rotational distributions are in good agreement with accurate quantum mechanical and approximate coupled states calculations. (C) 1999 American Institute of Physics. [S0021-9606(99)01221-0].
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页码:10231 / 10234
页数:4
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