Rotationally resolved differential scattering cross sections for the reaction F+para-H2 (v=0,j=0)→HF(v′=2,3,j′)+H

被引：34

作者：

Baer, M

Faubel, M

Martínez-Haya, B

Rusin, L

Tappe, U

Toennies, JP

机构：

[1] Max Planck Inst Stromungsforsch, D-37073 Gottingen, Germany

[2] SOREQ NRC, IL-81800 Yavne, Israel

[3] Russian Acad Sci, Inst Energy Problems Chem Phys, Moscow 117829, Russia

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 110卷 / 21期

关键词：

D O I：

10.1063/1.478955

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Time-of-flight spectra of HF products in the v' = 2 vibrational state from reactive scattering of F atoms from para-H-2 exhibit at least four smaller peaks which are assigned to the rotational states j' = 7, 8, 9, and 10. The center-of-mass rotational distributions are in good agreement with accurate quantum mechanical and approximate coupled states calculations. (C) 1999 American Institute of Physics. [S0021-9606(99)01221-0].

引用

收藏

页码：10231 / 10234

页数：4

相关论文

共 32 条

[1] Spin-orbit effects in the reaction of F(2P) with H2 [J].

Alexander, MH ;

Werner, HJ ;

Manolopoulos, DE .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (14) :5710-5713

[2] A TEST OF THE SEMICLASSICAL WIGNER METHOD FOR THE REACTION F+H-2-]H+HF [J].

AZRIEL, VM ;

BILLING, GD ;

RUSIN, LY ;

SEVRYUK, MB .

CHEMICAL PHYSICS, 1995, 195 (1-3) :243-258

[3] Integral and differential state-to-state cross-sections for the reactions F+D-2 (v(i)=O,j(i))->DF(v(f),j(f))+D: A comparison between three-dimensional quantum mechanical and experimental results [J].

Baer, M ;

Faubel, M ;

MartinezHaya, B ;

Rusin, LY ;

Tappe, U ;

Toennies, JP ;

Stark, K ;

Werner, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (07) :2743-2745

[4] QUANTUM-MECHANICAL CROSS-SECTIONS FOR THE D+H2 AND H+D2 REACTIVE SYSTEMS - APPLICATION OF THE NEGATIVE IMAGINARY POTENTIALS WITHIN THE J(Z)-APPROXIMATION [J].

BARAM, A ;

LAST, I ;

BAER, M .

CHEMICAL PHYSICS LETTERS, 1993, 212 (06) :649-653

[5] Quantum mechanical and quasiclassical simulations of molecular beam experiments for the F+H2→HF+H reaction on two ab initio potential energy surfaces [J].

Castillo, JF ;

Hartke, B ;

Werner, HJ ;

Aoiz, FJ ;

Bañares, L ;

Martínez-Haya, B .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (17) :7224-7237

[6] Quantum mechanical angular distributions for the F+H-2 reaction [J].

Castillo, JF ;

Manolopoulos, DE ;

Stark, K ;

Werner, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (17) :6531-6546

[7] Quantum state-resolved reactive scattering of F+H2 in supersonic jets:: Nascent HF(v,J) rovibrational distributions via IR laser direct absorption methods [J].

Chapman, WB ;

Blackmon, BW ;

Nizkorodov, S ;

Nesbitt, DJ .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (21) :9306-9317

[8] Angular dependence for v',j'-resolved states in F+H-2->HF(v',j')+H reactive scattering using a new atomic fluorine beam source [J].

Dharmasena, G ;

Copeland, K ;

Young, JH ;

Lasell, RA ;

Phillips, TR ;

Parker, GA ;

Keil, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (36) :6429-6440

[9] Rotational state resolved differential cross sections for the reaction F+D2→DF+D at collision energies 140-240 meV [J].

Faubel, M ;

Martínez-Haya, B ;

Rusin, LY ;

Tappe, U ;

Toennies, JP ;

Aoiz, FJ ;

Bañares, L .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (45) :8695-8707

[10] HIGH-RESOLUTION CROSSED MOLECULAR-BEAM INVESTIGATION OF THE ABSOLUTE CROSS-SECTIONS AND PRODUCT ROTATIONAL STATES FOR THE REACTION F+D-2, (V(I)=0 J(I)=0,1)-]DF(V(F)J(F))+D [J].

FAUBEL, M ;

RUSIN, L ;

SCHLEMMER, S ;

SONDERMANN, F ;

TAPPE, U ;

TOENNIES, JP .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (03) :2106-2125

← 1 2 3 4 →