Catalytic performance of MIL-100 (Fe, Cr) and MIL-101 (Fe, Cr) in the isomerization of endo- to exo-dicyclopentadiene

被引：38
作者：
Kim, Dong-Woo [1 ]
Kim, Hyeon-Gook [1 ]
Cho, Deug-Hee [1 ]
机构：
[1] Korea Res Inst Chem Technol, Div Ulsan Res Ctr Green Fine Chem, Ulsan 681802, South Korea
来源：
CATALYSIS COMMUNICATIONS | 2016年 / 73卷
关键词：
MOF; Isomerization; Dicyclopentadiene; Solvent-free; Acidic catalysis; METAL-ORGANIC FRAMEWORK; AEROBIC OXIDATION; CO2; CARBOXYLATE; LIQUID; OXIDE;
D O I：
10.1016/j.catcom.2015.10.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
MIL-100 (Fe, Cr) and MIL-101 (Fe, Cr), metal-organic frameworks (M0Fs), have been assessed in solvent-free isomerization of dicyclopentadiene (DCPD) from the endo- to exo-form. In the isomerization reaction, the conversion of endo-DCPD and selectivity for the exo-dimer strongly depend on the nature of the active metal center. The MIL-100 (Fe) catalyst possessing more acid sites shows the highest catalytic activity among the MILs and it was readily recoverable and reusable in subsequent reaction cycles for the isomerization. The effects of reaction parameters such as temperature, reaction time, and catalyst loading on the reactivity were also investigated. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：69 / 73
页数：5
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