The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis

被引:181
作者
Zander, Stefan [1 ]
Kunkes, Edward L. [1 ]
Schuster, Manfred E. [1 ]
Schumann, Julia [1 ]
Weinberg, Gisela [1 ]
Teschner, Detre [1 ]
Jacobsen, Nikolas [2 ]
Schloegl, Robert [1 ]
Behrens, Malte [1 ]
机构
[1] Max Planck Gesell, Dept Inorgan Chem, Fritz Haber Inst, D-14195 Berlin, Germany
[2] Clariant Prod Deutschland GmbH, BU Catalysts, Bruckmuhl, Germany
关键词
CO2; conversion; copper; magnesium; methanol synthesis; zinc; ZINC-OXIDE; CU; ZNO; PRECURSOR; BEHAVIOR; ROSASITE;
D O I
10.1002/anie.201301419
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The design of solid catalysts for industrial processes remains a major challenge in synthetic materials chemistry. Based on the investigation of the industrial Cu/ZnO/Al2O3 catalyst, a modular concept is introduced that helps to develop novel methanol synthesis catalysts that operate in different feed gas mixtures. SA=surface area, SMSI=strong metal-support interaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6536 / 6540
页数:5
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