Dodecaamide Cages: Organic 12-Arm Building Blocks for Supramolecular Chemistry

被引:47
作者
Culshaw, Jamie L.
Cheng, Ge
Schmidtmann, Marc
Hasell, Tom
Liu, Ming
Adams, Dave J. [1 ]
Cooper, Andrew I.
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
INTRINSIC MICROPOROSITY PIMS; POROUS DIPEPTIDE CRYSTALS; MOLECULAR CAGE; SOLIDS; POLYMERS; ROBUST; CO2;
D O I
10.1021/ja403987j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, one-step amidation reaction is used to produce a range of 12-arm organic building blocks for supramolecular chemistry via the derivatization of porous imine cages. As an example, microporous dendrimers are prepared.
引用
收藏
页码:10007 / 10010
页数:4
相关论文
共 44 条
[1]   Kinetically Controlled Porosity in a Robust Organic Cage Material [J].
Avellaneda, Antonio ;
Valente, Peter ;
Burgun, Alexandre ;
Evans, Jack D. ;
Markwell-Heys, Adrian W. ;
Rankine, Damien ;
Nielsen, David J. ;
Hill, Matthew R. ;
Sumby, Christopher J. ;
Doonan, Christian J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) :3746-3749
[2]   Heme-Like Coordination Chemistry Within Nanoporous Molecular Crystals [J].
Bezzu, C. Grazia ;
Helliwell, Madeleine ;
Warren, John E. ;
Allan, David R. ;
McKeown, Neil B. .
SCIENCE, 2010, 327 (5973) :1627-1630
[3]   Porous Organic Cage Compounds as Highly Potent Affinity Materials for Sensing by Quartz Crystal Microbalances [J].
Brutschy, Malte ;
Schneider, Markus W. ;
Mastalerz, Michael ;
Waldvogel, Siegfried R. .
ADVANCED MATERIALS, 2012, 24 (45) :6049-+
[4]   Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].
Budd, PM ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE .
CHEMICAL COMMUNICATIONS, 2004, (02) :230-231
[5]   Nanoporous Organic Polymer/Cage Composite Membranes [J].
Bushell, Alexandra F. ;
Budd, Peter M. ;
Attfield, Martin P. ;
Jones, James T. A. ;
Hasell, Tom ;
Cooper, Andrew I. ;
Bernardo, Paola ;
Bazzarelli, Fabio ;
Clarizia, Gabriele ;
Jansen, Johannes C. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (04) :1253-1256
[6]   Efficient cyclopropanation of C-60 starting from malonates [J].
Camps, X ;
Hirsch, A .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (11) :1595-1596
[7]   Soluble Conjugated Microporous Polymers [J].
Cheng, Ge ;
Hasell, Tom ;
Trewin, Abbie ;
Adams, Dave J. ;
Cooper, Andrew I. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (51) :12727-12731
[8]   Porous dipeptide crystals as selective CO2 adsorbents: experimental isotherms vs. grand canonical Monte Carlo simulations and MAS NMR spectroscopy [J].
Comotti, Angiolina ;
Fraccarollo, Alberto ;
Bracco, Silvia ;
Beretta, Mario ;
Distefano, Gaetano ;
Cossi, Maurizio ;
Marchese, Leonardo ;
Riccardi, Claudia ;
Sozzani, Piero .
CRYSTENGCOMM, 2013, 15 (08) :1503-1507
[9]   Methane, carbon dioxide and hydrogen storage in nanoporous dipeptide-based materials [J].
Comotti, Angiolina ;
Bracco, Silvia ;
Distefano, Gaetano ;
Sozzani, Piero .
CHEMICAL COMMUNICATIONS, 2009, (03) :284-286
[10]   Molecular Organic Crystals: From Barely Porous to Really Porous [J].
Cooper, Andrew I. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (32) :7892-7894