Cobalt-Catalyzed Decarboxylative Acetoxylation of Amino Acids and Arylacetic Acids

被引:50
|
作者
Xu, Kun [1 ]
Wang, Zhiqiang [1 ]
Zhang, Jinjin [1 ]
Yu, Lintao [1 ]
Tan, Jiajing [2 ]
机构
[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Henan, Peoples R China
[2] Merck Res Labs, Proc Chem, Rahway, NJ 07065 USA
关键词
ALIPHATIC CARBOXYLIC-ACIDS; C-H BOND; N-ACYLIMINIUM IONS; OXIDATIVE DECARBOXYLATION; COUPLING REACTIONS; BENZOIC-ACIDS; ARYL HALIDES; EFFICIENT METHOD; MILD CONDITIONS; ARYLATION;
D O I
10.1021/acs.orglett.5b02142
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first cobalt-catalyzed decarboxylative acetoxylation reaction was accomplished. This methodology is applicable to a wide range of amino acids and arylacetic acids.
引用
收藏
页码:4476 / 4478
页数:3
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