Lithium alloys and metal oxides as high-capacity anode materials for lithium-ion batteries

被引:250
作者
Liang, Chu
Gao, Mingxia [1 ]
Pan, Hongge
Liu, Yongfeng
Yan, Mi
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国博士后科学基金;
关键词
Lithium-ion batteries; Lithium alloys; Metal oxides; Electrochemical properties; Lithium storage mechanisms; SITU X-RAY; NEGATIVE-ELECTRODE MATERIALS; SN-C COMPOSITE; ELECTROCHEMICAL PERFORMANCE; FACILE SYNTHESIS; ALPHA-FE2O3; NANOTUBES; NANOCOMPOSITE ANODES; REVERSIBLE CAPACITY; CARBON NANOTUBES; AMORPHOUS OXIDE;
D O I
10.1016/j.jallcom.2013.04.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium alloys and metal oxides have been widely recognized as the next-generation anode materials for lithium-ion batteries with high energy density and high power density. A variety of lithium alloys and metal oxides have been explored as alternatives to the commercial carbonaceous anodes. The electrochemical characteristics of silicon, tin, tin oxide, iron oxides, cobalt oxides, copper oxides, and so on are systematically summarized. In this review, it is not the scope to retrace the overall studies, but rather to highlight the electrochemical performances, the lithium storage mechanism and the strategies in improving the electrochemical properties of lithium alloys and metal oxides. The challenges and new directions in developing lithium alloys and metal oxides as commercial anodes for the next-generation lithium-ion batteries are also discussed. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:246 / 256
页数:11
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