Efficient copper(I)-catalyzed coupling of secondary phosphine oxides with aryl halides

被引：51
|
作者：
Stankevic, Marek [1 ]
Wlodarczyk, Adam [1 ]
机构：
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Organ Chem, PL-20614 Lublin, Poland
来源：
TETRAHEDRON | 2013年 / 69卷 / 01期
关键词：
Coupling reaction; Copper(I) iodide; Secondary phosphine oxides; Tertiary phosphine oxides; Diphosphine dioxides; P BOND CONSTRUCTION; ASYMMETRIC HYDROGENATION; TERTIARY PHOSPHINES; CATALYZED FORMATION; OXAZOLINE LIGANDS; PHOSPHORUS; RESOLUTION; VERSATILE; BINAP; TRIARYLPHOSPHINES;
D O I：
10.1016/j.tet.2012.10.064
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A catalytic system has been developed for the efficient synthesis of tertiary arylphosphine oxides by coupling of readily available secondary phosphine oxides with aryl bromides or iodides in the presence of copper(I) iodide as a catalyst and (S)-alpha-phenylethylamine as a ligand. The system exhibits high activity in the coupling of secondary diaryl-, alkylaryl- and dialkylphosphine oxides. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：73 / 81
页数：9
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