Synthesis and X-ray characterization of novel palladium(II) complexes with tunable chiral anionic counterions

被引:4
|
作者
Cai, Yudong [1 ]
Shi, Yian [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
[2] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
关键词
METHYLPALLADIUM(II) ALKOXIDE COMPLEXES; SIMMONS-SMITH CYCLOPROPANATION; TRANSITION-METAL CATALYSIS; C-H ACTIVATION; CRYSTAL-STRUCTURES; BRONSTED ACID; DIALKYLPALLADIUM(II) COMPLEXES; ASYMMETRIC HYDROGENATION; REDUCTIVE ELIMINATION; ALPHA-ALLYLATION;
D O I
10.1039/c3dt00007a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Various novel palladium(II) complexes with tunable chiral and achiral anionic counterions have been prepared from dialkylpalladium(II) agents and characterized by NMR spectroscopy and X-ray diffraction.
引用
收藏
页码:5232 / 5236
页数:5
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