Structural and Optical Properties of N-Doped and B-Doped Carbon Dots

被引：13

作者：

Tomskaya, A. E. ^{[1
]}

Prosvirin, I. P. ^{[2
]}

Egorova, M. N. ^{[1
]}

Smagulova, S. A. ^{[1
]}

Asanov, I. P. ^{[3
]}

机构：

[1] Ammosov North Eastern Fed Univ, Yakutsk, Russia

[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk, Russia

[3] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 05期

关键词：

carbon dots; hydrothermal synthesis; luminescence; quantum yield; nitrogen; boron; BORON; NANOPARTICLES; MECHANISM;

D O I：

10.1134/S0022476620050194

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbon dots (CDs) demonstrate unique luminescence properties due to conjugated pi domains of thesp(2)/sp(3)hybridized carbon core, quantum-size effects, and passivation of CD surfaces by functional groups. In this work we present hydrothermal synthesis of nitrogen-doped and boron-doped CDs, their morphological, structural, optical characteristics, and luminescent properties. The CDs are first synthesized fromtrans-aconitic acid. X-ray photoelectron and infrared spectroscopy data indicate that prepared CDs contain nitrogen and boron atoms. The photoluminescence quantum yield of N-doped and B-doped CDs is 26% and 9%, respectively.

引用

页码：818 / 825

页数：8

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