A phthalimide-fused naphthalene diimide with high electron affinity for a high performance n-channel field effect transistor

被引:14
作者
Chang, Jingjing [1 ]
Shao, Jinjun [1 ]
Zhang, Jie [2 ]
Wu, Jishan [1 ,2 ]
Chi, Chunyan [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
ORGANIC TRANSISTORS; MATERIALS DESIGN; SEMICONDUCTORS; DERIVATIVES; TETRACENE; POLYMER;
D O I
10.1039/c3ra40504d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A phthalimide-fused naphthalene diimde (NDIIC24) with a low-lying LUMO energy level (-4.21 eV) and moderate solubility was synthesized. Organic field effect transistors (OFETs) based on solution processed thin films showed typical n-channel characteristics with a high electron mobility of 0.056 cm(2) V-1 s(-1) and a high on-off current ratio of 10(5)-10(6). The devices exhibited very good air stability and operating stability. Complementary inverters based on n-type NDIIC24 and p-type TIPS-pentacene demonstrated a maximum voltage gain (-dV(OUT)/dV(IN)) of 64.
引用
收藏
页码:6775 / 6778
页数:4
相关论文
共 31 条
[1]   n-Type Organic Semiconductors in Organic Electronics [J].
Anthony, John E. ;
Facchetti, Antonio ;
Heeney, Martin ;
Marder, Seth R. ;
Zhan, Xiaowei .
ADVANCED MATERIALS, 2010, 22 (34) :3876-3892
[2]   Stepwise Cyanation of Naphthalene Diimide for n-Channel Field-Effect Transistors [J].
Chang, Jingjing ;
Ye, Qun ;
Huang, Kuo-Wei ;
Zhang, Jie ;
Chen, Zhi-Kuan ;
Wu, Jishan ;
Chi, Chunyan .
ORGANIC LETTERS, 2012, 14 (12) :2964-2967
[3]   Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors [J].
Chen, Zhihua ;
Zheng, Yan ;
Yan, He ;
Facchetti, Antonio .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :8-+
[4]   Chain-length dependence of the electrochemical properties of conjugated oligofluorenes [J].
Chi, CY ;
Wegner, G .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (19) :1532-1537
[5]   A DFT study of the ground state multiplicities of linear vs angular polyheteroacenes [J].
Constantinides, CP ;
Koutentis, PA ;
Schatz, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) :16232-16241
[6]   Naphthoylene(trifluoromethylbenzimidazole)-dicarboxylic acid imides for high-performance n-type organic field-effect transistors [J].
Deng, Ping ;
Yan, Yan ;
Wang, Sui-Dong ;
Zhang, Qing .
CHEMICAL COMMUNICATIONS, 2012, 48 (20) :2591-2593
[7]   Organic and polymer transistors for electronics [J].
Dodabalapur, Ananth .
MATERIALS TODAY, 2006, 9 (04) :24-30
[8]   Semiconductors for organic transistors [J].
Facchetti, Antonio .
MATERIALS TODAY, 2007, 10 (03) :28-37
[9]   Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors [J].
Gao, Xike ;
Di, Chong-an ;
Hu, Yunbin ;
Yang, Xiaodi ;
Fan, Hongyu ;
Zhang, Feng ;
Liu, Yunqi ;
Li, Hongxiang ;
Zhu, Daoben .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (11) :3697-+
[10]   A β-naphthaleneimide-modified terthiophene exhibiting charge transfer and polarization through the short molecular axis.: Joint spectroscopic and theoretical study [J].
Gonzalez, Sandra R. ;
Casado, Juan ;
Navarrete, Juan T. Lopez ;
Blanco, Raul ;
Segura, Jose L. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (29) :6732-6740