N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure-photoluminescence property relationships in 2D and 1D lead-coordination polymers

被引：19

作者：

Toma, Oksana ^{[1
]}

Mercier, Nicolas ^{[1
]}

Bouilland, Mathilde ^{[1
]}

Allain, Magali ^{[1
]}

机构：

[1] MOLTECH Anjou, UMR CNRS 6200, F-49045 Angers, France

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 23期

关键词：

PHOTOPHYSICAL PROPERTIES; 4,4'-BIPYRIDINE-N,N'-DIOXIDE; COMPLEXES; TETRANUCLEAR; TOPOLOGIES; CHLORIDE; ANION; UNITS;

D O I：

10.1039/c2ce26237a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the strong orange luminescent material of [Pb(bp4mo)Cl-2], two different types of octahedra, namely PbCl4N2 and PbCl4O2, are bridged by the N-oxide-4,4'-bipyridine (bp4mo) ligand, while its protonated form, Hbp4mo(+), coordinates to Pb2+ center only with the N-oxide group in [Pb(Hbp4mo)(2) Cl-2](NO3)(2). Important relationships between structures and luminescence properties are revealed.

引用

收藏

页码：7844 / 7847

页数：4

相关论文

共 24 条

[11] 4,4′-bipyridine-N-monoxide.: A hybrid ligand for building networks using a combination of metal-ligand and hydrogen-bonding interactions [J].

Hoffart, Dennis J. ;

Habermehl, Nicolle C. ;

Loeb, Stephen J. .

DALTON TRANSACTIONS, 2007, (27) :2870-2875

[12] Space filling versus symmetry: Two consecutive crystal-to-crystal phase transitions in a 2D network [J].

Hu, Chunhua ;

Englert, Ulli .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (21) :3457-3459

[13] Multi-dimensional transition-metal coordination polymers of 4,4′-bipyridine-N,N′-dioxide:: 1D chains and 2D sheets [J].

Jia, Junhua ;

Blake, Alexander J. ;

Champness, Neil R. ;

Hubberstey, Peter ;

Wilson, Claire ;

Schroder, Martin .

INORGANIC CHEMISTRY, 2008, 47 (19) :8652-8664

[14] Synthesis, structure, and luminescence of a novel lead(II) coordination polymer with 1,2-phenylenediacetic acid [J].

Lei, Zhi-Hong ;

Li, Xia ;

Dong, Li-Na .

INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (12) :1383-1386

[15] Synthesis, crystal structures, and photophysical properties of two novel lead(II)-SIP coordination polymers (NaH2SIP=5-sulfoisophthalic acid monosodium salt) containing tetranuclear lead(II) units [J].

Liu, QY ;

Xu, L .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (08) :1620-1628

[16] Lanthanum coordination networks based on unusual five-connected topologies [J].

Long, DL ;

Blake, AJ ;

Champness, NR ;

Wilson, C ;

Schröder, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (14) :3401-3402

[17] Luminescent lead(II) complexes: new three-dimensional mixed ligand MOFs [J].

Martinez Casado, Francisco Javier ;

Canadillas-Delgado, Laura ;

Cucinotta, Fabio ;

Guerrero-Martinez, Andres ;

Ramos Riesco, Miguel ;

Marchese, Leonardo ;

Rodriguez Cheda, Jose Antonio .

CRYSTENGCOMM, 2012, 14 (08) :2660-2668

[18] PHOTOLUMINESCENCE OF GERMANIUM(II), TIN(II), AND LEAD(II) CHLORIDE COMPLEXES IN SOLUTION [J].

NIKOL, H ;

BECHT, A ;

VOGLER, A .

INORGANIC CHEMISTRY, 1992, 31 (15) :3277-3279

[19] Hydrothermal synthesis of two new lead-containing coordination polymers:: 2∞[Pb2Cl2(4,4′-bipy)] and 2∞[Pb2(NO3)4(H2O)2(4,4′-bipy)2](4,4′-bipy)2 [J].

Nordell, KJ ;

Schultz, KN ;

Higgins, KA ;

Smith, MD .

POLYHEDRON, 2004, 23 (13) :2161-2167

[20] HARD AND SOFT ACIDS AND BASES [J].

PEARSON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (22) :3533-&