N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure-photoluminescence property relationships in 2D and 1D lead-coordination polymers

被引：19

作者：

Toma, Oksana ^{[1
]}

Mercier, Nicolas ^{[1
]}

Bouilland, Mathilde ^{[1
]}

Allain, Magali ^{[1
]}

机构：

[1] MOLTECH Anjou, UMR CNRS 6200, F-49045 Angers, France

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 23期

关键词：

PHOTOPHYSICAL PROPERTIES; 4,4'-BIPYRIDINE-N,N'-DIOXIDE; COMPLEXES; TETRANUCLEAR; TOPOLOGIES; CHLORIDE; ANION; UNITS;

D O I：

10.1039/c2ce26237a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the strong orange luminescent material of [Pb(bp4mo)Cl-2], two different types of octahedra, namely PbCl4N2 and PbCl4O2, are bridged by the N-oxide-4,4'-bipyridine (bp4mo) ligand, while its protonated form, Hbp4mo(+), coordinates to Pb2+ center only with the N-oxide group in [Pb(Hbp4mo)(2) Cl-2](NO3)(2). Important relationships between structures and luminescence properties are revealed.

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收藏

页码：7844 / 7847

页数：4

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