Enantio- and periselective nitroalkene Diels-Alder reaction

被引：16

作者：

Narcis, Maurice J. ^{[1
]}

Sprague, Daniel J.

Captain, Burjor ^{[1
]}

Takenaka, Norito ^{[1
]}

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 46期

基金：

美国国家科学基金会;

关键词：

HIGHLY FUNCTIONALIZED CYCLOPENTENES; CATALYTIC ASYMMETRIC-SYNTHESIS; 2-AMINOPYRIDINIUM IONS; BOND DONORS; OLEFINS; ACID; OXAZABOROLIDINE; CYCLOADDITIONS; ACTIVATION; PRODUCTS;

D O I：

10.1039/c2ob26674a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The periselective Diels-Alder reaction of 5-substituted penta-methylcyclopentadienes and nitroethylene has been realized by helical-chiral hydrogen bond donor catalysts. To our knowledge, this represents the first asymmetric catalytic nitroalkene Diels-Alder reaction via activation of nitroalkene, and thus establishes its proof-of-principle.

引用

页码：9134 / 9136

页数：3

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