Enantio- and periselective nitroalkene Diels-Alder reaction

被引：16
|
作者：
Narcis, Maurice J. [1 ]
Sprague, Daniel J.
Captain, Burjor [1 ]
Takenaka, Norito [1 ]
机构：
[1] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 46期
基金：
美国国家科学基金会;
关键词：
HIGHLY FUNCTIONALIZED CYCLOPENTENES; CATALYTIC ASYMMETRIC-SYNTHESIS; 2-AMINOPYRIDINIUM IONS; BOND DONORS; OLEFINS; ACID; OXAZABOROLIDINE; CYCLOADDITIONS; ACTIVATION; PRODUCTS;
D O I：
10.1039/c2ob26674a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The periselective Diels-Alder reaction of 5-substituted penta-methylcyclopentadienes and nitroethylene has been realized by helical-chiral hydrogen bond donor catalysts. To our knowledge, this represents the first asymmetric catalytic nitroalkene Diels-Alder reaction via activation of nitroalkene, and thus establishes its proof-of-principle.
引用
收藏
页码：9134 / 9136
页数：3
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