Observation of Rapid Desolvation of Hexafluorobenzene Involving Single-Crystal-to-Single-Crystal Phase Transition in a Nonporous Organic Host

被引：8

作者：

Bhandary, Subhrajyoti ^{[1
]}

Chopra, Deepak ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Crystallog & Crystal Chem Lab, Bhopal By Pass Rd, Bhopal 462066, Madhya Pradesh, India

来源：

CRYSTAL GROWTH & DESIGN | 2018年 / 18卷 / 01期

关键词：

TRANSFORMATION; POLYMORPHISM; BEHAVIOR;

D O I：

10.1021/acs.cgd.7b01309

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report an unusual occurrence of an extremely fast single crystal-to-single-crystal phase transition induced by rapid desolvation of hexafluorobenzene at room temperature mediated by a subtle interplay of pi-pi stacking interactions in N-(3-ethynylphenyl)-4-fluorobenzamide. The nature of the host guest stacking interaction'has been explored in terms of interaction energy, electrostatic complementarity, and topological analysis with the inputs from reduced density gradient-noncovalent interactions fingerprint descriptor. Furthermore, the compound also exists in two other nonsolvated polymorphic forms.

引用

页码：27 / 31

页数：5

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