Influence of silver and copper doping on luminescent properties of zinc-phosphate glasses after x-ray irradiation

被引：2

作者：

Murashov, Alexander A. ^{[1
]}

Sidorov, Alexander I. ^{[1
]}

Shakhverdov, Teimur A. ^{[1
]}

Stolyarchuk, Maxim V. ^{[1
]}

机构：

[1] ITMO Univ, Dept Photon & Optoinformat, St Petersburg, Russia

来源：

OPTICAL ENGINEERING | 2017年 / 56卷 / 11期

关键词：

luminescence; glass; silver; copper; molecular cluster; SILICATE-GLASSES; MOLECULAR CLUSTERS; OPTICAL-PROPERTIES; SPECTRA; ION; METAL; ABSORPTION; CENTERS; ATOMS; BLUE;

D O I：

10.1117/1.OE.56.11.117106

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

It is shown, experimentally, that in silver- and copper-containing zinc-phosphate glasses, metal molecular clusters are formed during the glass synthesis. X-ray irradiation of these glasses led to the considerable increase of its luminescence in visible spectral range. This effect is caused by the transformation of the charged metal molecular clusters into the neutral state. Luminescence and excitation spectra of the glass, doped with silver and copper simultaneously, change significantly in comparison with the spectra of glasses doped with one metal. The reason for this can be the formation of hybrid AgnCum molecular clusters. The computer simulation of the structure and optical properties of such clusters by the time-dependent density functional theory method is presented. It is shown that the optimal luminescent material for photonics application, in comparison with other studied materials, is glass, containing hybrid molecular clusters. (c) 2017 Society of Photo-Optical Instrumentation Engineers (SPIE)

引用

页数：6

共 54 条

[21] Copper clusters and small particles stabilized within nanoporous materials [J].

Gurin, VS ;

Petranovskii, VP ;

Pestryakov, AN ;

Kryazhov, A ;

Ozhereliev, O ;

Hernandes, MA ;

Alexeenko, AA .

EUROPEAN PHYSICAL JOURNAL D, 2003, 24 (1-3) :381-384

[22] Influence of UV irradiation and heat treatment on the luminescence of molecular silver clusters in photo-thermo-refractive glasses [J].

Ignat'ev, A. I. ;

Nikonorov, N. V. ;

Sidorov, A. I. ;

Shakhverdov, T. A. .

OPTICS AND SPECTROSCOPY, 2013, 114 (05) :769-774

[23] Formation of Silver Nanoparticles in Photothermorefractive Glasses during Electron Irradiation [J].

Ignat'ev, A. I. ;

Nashchekin, A. V. ;

Nevedomskii, V. M. ;

Podsvirov, O. A. ;

Sidorov, A. I. ;

Solov'ev, A. P. ;

Usov, O. A. .

TECHNICAL PHYSICS, 2011, 56 (05) :662-667

[24] Formation of luminescent centers in photo-thermo-refractive silicate glasses under the action of UV laser nanosecond pulses [J].

Ignatiev, A. I. ;

Klyukin, D. A. ;

Leontieva, V. S. ;

Nikonorov, N. V. ;

Shakhverdov, T. A. ;

Sidorov, A. I. .

OPTICAL MATERIALS EXPRESS, 2015, 5 (07) :1635-1646

[25] Structural and electronic properties of small bimetallic Ag-Cu clusters [J].

Kilimis, D. A. ;

Papageorgiou, D. G. .

EUROPEAN PHYSICAL JOURNAL D, 2010, 56 (02) :189-197

[26] VERY SMALL BIMETALLIC CLUSTERS OF SILVER WITH MANGANESE, MOLYBDENUM, AND COPPER IN RARE-GAS MATRICES [J].

KLOTZBUCHER, WE ;

OZIN, GA .

INORGANIC CHEMISTRY, 1980, 19 (12) :3776-3782

[27] Formation of luminescence centers and nonlinear optical effects in silver-containing glasses under femtosecond laser pulses [J].

Klyukin, D. A. ;

Sidorov, A. I. ;

Ignatiev, A. I. ;

Nikonorov, N. V. ;

Silvennoinen, M. ;

Svirko, Yu. P. .

OPTICS AND SPECTROSCOPY, 2015, 119 (03) :456-459

[28] Luminescence quenching and recovering in photo-thermo-refractive silver-ion doped glasses [J].

Klyukin, D. A. ;

Sidorov, A. I. ;

Ignatiev, A. I. ;

Nikonorov, N. V. .

OPTICAL MATERIALS, 2014, 38 :233-237

[29] OPTICAL-SPECTRUM OF MATRIX-ISOLATED CU2 [J].

KOLB, DM ;

ROTERMUND, HH ;

SCHRITTENLACHER, W ;

SCHROEDER, W .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (02) :695-700

[30] Polarization memory of white luminescence of Ag nanoclusters dispersed in glass host [J].

Kuznetsov, A. S. ;

Tikhomirov, V. K. ;

Moshchalkov, V. V. .

OPTICS EXPRESS, 2012, 20 (19) :21576-21582

← 1 2 3 4 5 6 →