Zinc cadmium thiocyanate (ZCTC)

被引:20
作者
Tian, YP [1 ]
Yu, WT [1 ]
Fang, Q [1 ]
Wang, XQ [1 ]
Yuan, DR [1 ]
Xu, D [1 ]
Jiang, MH [1 ]
机构
[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
关键词
D O I
10.1107/S0108270199007623
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title complex, zinc cadmium tetrathiocyanate, [ZnCd(SCN)(4)](n), contains slightly flattened ZnN4 and CdS4 tetrahedra. The -S=C=N- bridges connect Zn and Cd atoms, forming infinite three-dimensional -Cd-S=C=N-Zn- networks, and are essentially linear at C and N, but bent at S. The structure exhibits a high non-linear optical property, and physical and chemical stability.
引用
收藏
页码:1393 / 1395
页数:3
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