Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex

被引：58

作者：

Wei, WL ^{[1
]}

Zhu, HY ^{[1
]}

Zhao, CL ^{[1
]}

Huang, MY ^{[1
]}

Jiang, YY ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2004年 / 59卷 / 01期

关键词：

silica-supported alginic acid-amino acid-Pt complex; asymmetric hydrogenation; furfuryl alcohol; (S)-(+)-tetrahydrofurfuryl alcohol;

D O I：

10.1016/j.reactfunctpolym.2003.10.004

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A biopolymer containing metal complex, silica-supported alginic acid-amino acid (L-alanine, L-glutamic acid, L-serine or L-lysine)-Pt complex, SiO2-AA-aa-Pt (SiO2-AA-ala-Pt, SiO2-AA-glu-Pt, SiO2-AA-ser-Pt, SiO2-AA-lys-Pt) has been prepared and found to be able to catalyze the asymmetric hydrogenation of furfuryl alcohol to give (S)(+)-tetrahydrofurfuryl alcohol at 30 degreesC and under 1 atmH(2). Among of them, SiO2-AA-glu-Pt complex catalyst is most effective for this asymmetric reaction and 84.4% product yield and 98.3% ee optical yield can be obtained, respectively. This catalyst can be reused several times without large change in the optical catalytic activity. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：33 / 39

页数：7

共 9 条

[1]

FREDERICK C, 1964, J ORG CHEM, V29, P873

[2] Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol [J].

Huang, K ;

Xue, L ;

Huang, MY ;

Jiang, YY .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2002, 13 (3-4) :165-168

[3] Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone [J].

Huang, K ;

Xue, L ;

Hu, YC ;

Huang, MY ;

Jiang, YY .

REACTIVE & FUNCTIONAL POLYMERS, 2002, 50 (03) :199-203

[4]

JIN MY, 1999, J MOL CATAL A-CHEM, V147, P89

[5]

JIN MY, 1999, J MOL CATAL A-CHEM, V147, P93

[6]

Noyori R., 1993, Asymmetric catalysis in organic synthesis

[7] Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone [J].

Xue, L ;

Li, BY ;

Huang, MY ;

Jiang, YY .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2003, 14 (3-5) :282-286

[8]

Yuan GL, 1999, POLYM ADVAN TECHNOL, V10, P442, DOI 10.1002/(SICI)1099-1581(199907)10:7<442::AID-PAT892>3.0.CO

[9]

2-X

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