Risk assessment of airborne pesticides in a Mediterranean region of Spain

被引:48
作者
Lopez, Antonio [1 ,2 ,3 ,5 ]
Yusa, Vicent [1 ,2 ,3 ,5 ]
Munoz, Amalia [4 ,5 ]
Vera, Teresa [4 ,5 ]
Borras, Esther [4 ,5 ]
Rodenas, Milagros [4 ,5 ]
Coscolla, Clara [1 ,3 ,5 ]
机构
[1] FISABIO Publ Hlth, Fdn Promot Hlth & Biomed Res Valencian Reg, 21 Ave Catalunya, Valencia 46020, Spain
[2] Univ Valencia, Dept Analyt Chem, Edifici Jeroni Munoz,Dr Moliner 50, E-46100 Burjassot, Spain
[3] Publ Hlth Lab Valencia, 21 Ave Catalunya, Valencia 46020, Spain
[4] Inst Univ UHM CEAM, C Charles Darwin 14,Parque Tecnol, Valencia 46980, Spain
[5] Atmospher Pesticide Res Grp Valencia, Valencia, Spain
关键词
Pesticides; Ambient air; Risk assessment; Gas/particle partitioning; ORGANOPHOSPHORUS PESTICIDES; CONTEMPORARY PESTICIDES; ATMOSPHERIC DEGRADATION; MS CHARACTERIZATION; VALENCIA REGION; CHROMATOGRAPHY; CHLORPYRIFOS; CALIFORNIA; COMMUNITY; EXPOSURE;
D O I
10.1016/j.scitotenv.2016.08.149
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A risk assessment strategy based on the quantitative target analysis and semi-quantitative retrospective screening determination of pesticides in PM10 has been developed. The proposed methodology was applied to 345 real samples from nine stations of a Mediterranean area in Spain, and the risk was assessed for adult, children and infants. Forty pesticides were detected with average concentrations ranging from 8 to 30,000 pg m(-3). Each station showed its specific pesticide profile, which is linked to the different types of crops around each station. For adults, children and infants the estimated chronic inhalation risk, expressed as Hazard Quotient (HQ), was <1 for all pesticides. The cumulative exposure for organophosphates, neonicotinoids, benzimidazoles, carbamates, microorganism and triazoles pesticides (HI, Hazard Index) were <1 for the three groups of populations assessed. For infants, the cancer risk estimated for the detected pesticides classified as possible and potential carcinogens were lower than 1.0 E-06, except for carbendazim and hexythiazox. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:724 / 734
页数:11
相关论文
共 55 条
  • [31] Qualitative aspects and validation of a screening method for pesticides in vegetables and fruits based on liquid chromatography coupled to full scan high resolution (Orbitrap) mass spectrometry
    Mol, Hans G. J.
    Zomer, Paul
    de Koning, Maarten
    [J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 403 (10) : 2891 - 2908
  • [32] The gas-phase degradation of chlorpyrifos and chlorpyrifos-oxon towards OH radical under atmospheric conditions
    Munoz, Amalia
    Rodenas, Milagros
    Borras, Esther
    Vazquez, Monica
    Vera, Teresa
    [J]. CHEMOSPHERE, 2014, 111 : 522 - 528
  • [33] Studies on atmospheric degradation of diazinon in the EUPHORE simulation chamber
    Munoz, Amalia
    Le Person, Annaig
    Le Calve, Stephane
    Mellouki, Abdelwahid
    Borras, Esther
    Daele, Veronique
    Vera, Teresa
    [J]. CHEMOSPHERE, 2011, 85 (05) : 724 - 730
  • [34] Studies on the Atmospheric Degradation of Chlorpyrifos-Methyl
    Munoz, Amalia
    Vera, Teresa
    Sidebottom, Howard
    Mellouki, Abdelwahid
    Borras, Esther
    Rodenas, Milagros
    Clemente, Eva
    Vazquez, Monica
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (05) : 1880 - 1886
  • [35] National Center for Biotechnology Information, 2004, PUBCHEM COMP DAT
  • [36] Gas-phase concentrations of current-use pesticides in Iowa
    Peck, AM
    Hornbuckle, KC
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (09) : 2952 - 2959
  • [37] Pesticides T, 2014, DAT COMP LIB ENV FOO
  • [38] Trace level determination of selected organophosphorus pesticides and their degradation products in environmental air samples by liquid chromatography-positive ion electrospray tandem mass spectrometry
    Raina, Renata
    Sun, Lina
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 2008, 43 (04) : 323 - 332
  • [39] Royal Society of Chemistry, 2011, CHEMSPIDER SOFTW
  • [40] Sampling of organophosphorus pesticides at trace levels in the atmosphere using XAD-2 adsorbent and analysis by gas chromatography coupled with nitrogen-phosphorus and ion-trap mass spectrometry detectors
    Russo, Mario Vincenzo
    Avino, Pasquale
    Cinelli, Giuseppe
    Notardonato, Ivan
    [J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 404 (05) : 1517 - 1527