Synthesis, structure, and reactions of a nitroxyl complex of iridium(III), cis,trans-IrHCl2(NH=O)(PPh3)2

被引：34

作者：

Melenkivitz, R ^{[1
]}

Hillhouse, GL ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Searle Chem Lab, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111645b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Ir(NO)(PPh3)(3) with anhydrous HCl results in addition of 2 equivalents of HCl with formal protonation of the nitrosyl ligand, affording the unusual six-co-ordinate nitroxyl complex cis,trans-IrHCl2(NH=O)(PPh3)(2).

引用

页码：660 / 661

页数：2

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