Oxidation resistant SiC coating for graphite materials

被引：140
作者：
Zhu, QS [1 ]
Qiu, XL [1 ]
Ma, CW [1 ]
机构：
[1] Tsing Hua Univ, Inst Nucl Energy Technol, Beijing 100080, Peoples R China
来源：
CARBON | 1999年 / 37卷 / 09期
关键词：
graphite; coating; oxidation;
D O I：
10.1016/S0008-6223(99)00010-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A dense functional gradient SiSiC coating with good oxidation resistance when applied to a graphite substrate has been developed using a novel process, in which large pores in the coating were eliminated by application of a primary coating, and pinholes were filled with free silicon. The mechanism for the formation of a continuous SIC coating on graphite was investigated experimentally and theoretically. Oxidation tests were conducted from 800 degrees C to 1600 degrees C for up to 1000 h. Samples of graphite with the SiSiC coating were found to be totally intact after oxidizing for 1000 h together with 100 thermal cycles at 1200 degrees C and 200 h with 20 thermal cycles at 1400 degrees C, indicating excellent oxidation resistance and thermal shock resistance of the coating. The good thermal shock resistance is attributed to the compositional gradient in the coating. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1475 / 1484
页数：10
相关论文
共 35 条
  • [1] [Anonymous], CERAMIC B
  • [2] ACTIVE TO PASSIVE TRANSITION IN THE OXIDATION OF SILICON-CARBIDE AT HIGH-TEMPERATURE AND LOW-PRESSURE IN MOLECULAR AND ATOMIC OXYGEN
    BALAT, M
    FLAMANT, G
    MALE, G
    PICHELIN, G
    [J]. JOURNAL OF MATERIALS SCIENCE, 1992, 27 (03) : 697 - 703
  • [3] OXIDATION PROTECTION OF CARBON-CARBON COMPOSITES USING CHEMICAL-VAPOR-DEPOSITION AND GLAZE TECHNOLOGY
    BUCHANAN, FJ
    LITTLE, JA
    [J]. CORROSION SCIENCE, 1993, 35 (5-8) : 1243 - 1250
  • [4] REACTION-FORMED SILICON-CARBIDE
    CHIANG, YM
    MESSNER, RP
    TERWILLIGER, CD
    BEHRENDT, DR
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1991, 144 : 63 - 74
  • [5] OXIDATION-RESISTANT CARBON-CARBON COMPOSITES UP TO 1700-DEGREES-C
    DHAMI, TL
    BAHL, OP
    AWASTHY, BR
    [J]. CARBON, 1995, 33 (04) : 479 - 490
  • [6] SILICON-CARBIDE/BORON-CONTAINING COATINGS FOR THE OXIDATION PROTECTION OF GRAPHITE
    FERGUS, JW
    WORRELL, WL
    [J]. CARBON, 1995, 33 (04) : 537 - 543
  • [7] FROM SILICON TO CARBON
    FITZER, E
    [J]. CARBON, 1978, 16 (01) : 3 - 16
  • [8] Fitzer E., 1992, HIGH TEMP-HIGH PRESS, V24, P343
  • [9] IMPROVEMENT OF THE OXIDATION RESISTANCE OF A GRAPHITE MATERIAL BY COMPOSITIONALLY GRADIENT SIC/C LAYER
    FUJII, K
    NAKANO, J
    SHINDO, M
    [J]. JOURNAL OF NUCLEAR MATERIALS, 1993, 203 (01) : 10 - 16
  • [10] FORMATION PROCESS OF BETA-SIC DURING REACTION-SINTERING
    HASE, T
    SUZUKI, H
    ISEKI, T
    [J]. JOURNAL OF NUCLEAR MATERIALS, 1976, 59 (01) : 42 - 48
1234