Engineering polarization rotation in ferroelectric bismuth titanate

被引:19
作者
Roy, Amritendu [1 ]
Prasad, Rajendra [2 ]
Auluck, Sushil [3 ]
Garg, Ashish [1 ]
机构
[1] Indian Inst Technol, Dept Mat Sci & Engn, Kanpur 208016, Uttar Pradesh, India
[2] Indian Inst Technol, Dept Phys, Kanpur 208016, Uttar Pradesh, India
[3] Natl Phys Lab, New Delhi 110012, India
关键词
THIN-FILMS; ORIENTATION; GROWTH; PHASE;
D O I
10.1063/1.4804367
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report a combined experimental-theoretical study showing that collective application of rare earth doping on Bi-site of ferroelectric bismuth titanate (Bi4Ti3O12) and epitaxial strain leads to only a small increase in c-axis polarization, resolving conflicts of previous experimental data on c-axis oriented thin films. However, as shown by our first principles calculations, a modest c-axis polarization can be induced by simultaneous Bi(A) and Ti(B) site doping in bismuth titanate. This approach, correlating doping, epitaxial strain, and polarization in ferroic oxides, could be useful to tailor oxide compositions, assisting in the growth of epitaxial films along easy growth directions yielding reasonable polarization. (C) 2013 AIP Publishing LLC.
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页数:5
相关论文
共 32 条
[1]  
Achary SN, 2008, PRAMANA-J PHYS, V71, P935, DOI 10.1007/s12043-008-0203-0
[2]  
Bosquet E., 2010, PHYS REV B, V82
[3]   First-principles study of ferroelectric and nonlinear optical property in bismuth titanate [J].
Cai, MQ ;
Yin, Z ;
Zhang, MS ;
Li, YZ .
CHEMICAL PHYSICS LETTERS, 2005, 401 (4-6) :405-409
[4]  
Catalan G, 2011, NAT MATER, V10, P963, DOI [10.1038/nmat3141, 10.1038/NMAT3141]
[5]   Low-Symmetry Monoclinic Phases and Polarization Rotation Path Mediated by Epitaxial Strain in Multiferroic BiFeO3 Thin Films [J].
Chen, Zuhuang ;
Luo, Zhenlin ;
Huang, Chuanwei ;
Qi, Yajun ;
Yang, Ping ;
You, Lu ;
Hu, Chuansheng ;
Wu, Tom ;
Wang, Junling ;
Gao, Chen ;
Sritharan, Thirumany ;
Chen, Lang .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (01) :133-138
[6]   Orientation dependent ferroelectric properties in samarium doped bismuth titanate thin films grown by the pulsed-laser-ablation method [J].
Cheng, Zhenxiang ;
Kannan, Chinna Venkatasamy ;
Ozawa, Kiyoshi ;
Kimura, Hideo ;
Wang, Xiaolin .
APPLIED PHYSICS LETTERS, 2006, 89 (03)
[7]   Layered perovskites with giant spontaneous polarizations for nonvolatile memories [J].
Chon, U ;
Jang, HM ;
Kim, MG ;
Chang, CH .
PHYSICAL REVIEW LETTERS, 2002, 89 (08) :1-087601
[8]   Ferroelectric properties and crystal structure of praseodymium-modified bismuth titanate [J].
Chon, U ;
Shim, JS ;
Jang, HM .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (08) :4769-4775
[9]   Fatigue-free samarium-modified bismuth titanate (Bi4-xSmxTi3O12) film capacitors having large spontaneous polarizations [J].
Chon, U ;
Kim, KB ;
Jang, HM ;
Yi, GC .
APPLIED PHYSICS LETTERS, 2001, 79 (19) :3137-3139
[10]   LOW-TEMPERATURE GROWTH OF BI4TI3O12 EPITAXIAL-FILMS ON SRTIO3(001) AND BI2SR2CACU2O8(001) SINGLE-CRYSTALS BY LASER MOLECULAR-BEAM EPITAXY [J].
CHOOPUN, S ;
MATSUMOTO, T ;
KAWAI, T .
APPLIED PHYSICS LETTERS, 1995, 67 (08) :1072-1074