trans-diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]-manganese(II)

被引:15
作者
Chen, Li-Zhuang [1 ]
机构
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Coll Chem & Chem Engn, Nanjing 210096, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808029073
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Mn(C10H6N3O4)(2)(H2O)(2)], synthesized by hydrothermal reaction, the Mn II ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N-H center dot center dot center dot O, O-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen-bonding interactions.
引用
收藏
页码:M1286 / U624
页数:10
相关论文
共 5 条
[1]   Two stable 3D metal-organic frameworks constructed by nanoscale cages via sharing the single-layer walls [J].
Lu, WG ;
Su, CY ;
Lu, TB ;
Jiang, L ;
Chen, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) :34-35
[2]  
Rigaku, 2005, CRYSTALCLEAR
[3]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[4]   Diaquabis(1H-imidazole-4,5-dicarboxylato-κN3)-cobalt(II) N,N-dimethylformamide disolvate [J].
Xiao, HP ;
Li, XH ;
Shi, Q .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M1519-M1521
[5]   trans-diapuabis(1H-imidazole-4,5-dicarboxylato-κ2N3,O4)cadmium(II) [J].
Zhang, XM ;
Fang, RQ ;
Wu, HS ;
Ng, SW .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M12-M13