Design and Synthesis of Novel 2D Porous Zinc Oxide-Nickel Oxide Composite Nanosheets for Detecting Ethanol Vapor

The porous zinc oxide-nickel oxide (ZnO-NiO) composite nanosheets were synthesized via sputtering deposition of NiO thin film on the porous ZnO nanosheet templates. Various NiO film coverage sizes on porous ZnO nanosheet templates were achieved by changing NiO sputtering duration in this study. The microstructures of the porous ZnO-NiO composite nanosheets were investigated herein. The rugged surface feature of the porous ZnO-NiO composite nanosheets were formed and thicker NiO coverage layer narrowed the pore size on the ZnO nanosheet template. The gas sensors based on the porous ZnO-NiO composite nanosheets displayed higher sensing responses to ethanol vapor in comparison with the pristine ZnO template at the given target gas concentrations. Furthermore, the porous ZnO-NiO composite nanosheets with the suitable NiO coverage content demonstrated superior gas-sensing performance towards 50-750 ppm ethanol vapor. The observed ethanol vapor-sensing performance might be attributed to suitable ZnO/NiO heterojunction numbers and unique porous nanosheet structure with a high specific surface area, providing abundant active sites on the surface and numerous gas diffusion channels for the ethanol vapor molecules. This study demonstrated that coating of NiO on the porous ZnO nanosheet template with a suitable coverage size via sputtering deposition is a promising route to fabricate porous ZnO-NiO composite nanosheets with a high ethanol vapor sensing ability.