Simultaneous Free-Radical and Addition Miniemulsion Polymerization: Effect of the Chain Transfer Agent on the Microstructure of Polyurethane-Acrylic Pressure-Sensitive Adhesives

被引：28

作者：

Lopez, Aitziber ^{[1
,2
]}

Reyes, Yuri ^{[1
,2
]}

Degrandi-Contraires, Elise ^{[3
]}

Canetta, Elisabetta ^{[4
]}

Creton, Costantino ^{[3
]}

Keddie, Joseph L. ^{[4
]}

Asua, Jose M. ^{[1
,2
]}

机构：

[1] Univ Basque Country UPV EHU, POLYMAT, Donostia San Sebastian 20018, Spain

[2] Univ Basque Country UPV EHU, Dpto Quim Aplicada, Grp Ingn Quim, Donostia San Sebastian 20018, Spain

[3] ESPCI, CNRS, Lab Physicochim Polymeres & Milieux Disperses, F-75231 Paris 05, France

[4] Univ Surrey, Dept Phys, Fac Engn & Phys Sci, Guildford GU2 7XH, Surrey, England

来源：

MACROMOLECULAR MATERIALS AND ENGINEERING | 2013年 / 298卷 / 01期

关键词：

adhesives; crosslinking; miniemulsion polymerization; Monte Carlo simulation; structure-property relations; BISPHENOL-A DERIVATIVES; EMULSION POLYMERIZATION; HYBRID LATEXES; DODECYL MERCAPTAN; METHACRYLATE; KINETICS; REACTIVITY; CONVERSION; SCAVENGERS; PARTICLES;

D O I：

10.1002/mame.201100390

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effects of the CTA concentration on polymerization kinetics, polymer microstructure, particle morphology, and adhesive performance of waterborne hybrid PSAs prepared by simultaneous free-radical and addition miniemulsion polymerizations are studied. The development of the microstructure is shown to differ from waterborne acrylic PSAs obtained by free-radical polymerization because of the contribution of the addition reaction, which in turn causes marked differences in the adhesive performance of the final films. A computer simulation is developed to obtain detailed information about the microstructure of PU/acrylic hybrids and to correlate the microstructure with the final adhesive properties.

引用

页码：53 / 66

页数：14

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