Domino Intramolecular Ring-Closing Metathesis/Cross-Metathesis Reaction: Total Synthesis of Putative Structure of Cryptopyranmoscatone A2

被引：0

作者：

Kundeti, Lakshmi Srinivasa Rao ^{[1
]}

Chinnam, Vijaya Vardhan ^{[1
,2
]}

Sharada, Ambati ^{[1
]}

Sarma, Akella Venkata Subrahmanya ^{[3
]}

Kommu, Nagaiah ^{[1
]}

Yadav, Jhillu Singh ^{[1
,4
]}

机构：

[1] CSIR Indian Inst Chem Technol, Ctr Nat Prod Chem Div, Hyderabad 500007, Telangana, India

[2] Govt Degree Coll, East Godavari 533449, Andhra Pradesh, India

[3] CSIR Indian Inst Chem Technol, Dept Analyt & Struct Chem, Hyderabad 500007, Telangana, India

[4] Indrashil Univ, Sch Sci, Mehsana 382740, Gujarat, India

来源：

CHEMISTRYSELECT | 2022年 / 7卷 / 44期

关键词：

Brown asymmetric allylation; Grieco elemination; Hydroboration-Oxidation; RCM and CM; Upjohn conditions; FORMAL TOTAL-SYNTHESIS; STYRYL-LACTONES; STEREOSELECTIVE-SYNTHESIS; CYTOTOXICITY; ALCOHOLS; FRAGMENT; STEREOCHEMISTRY; OXIDATION; REMOVAL;

D O I：

10.1002/slct.202202806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereoselective total synthesis of Putative structure of the Cryptopyranmoscatone A2 is presented, starting from epichlorohydrin. Key step in the synthesis involved a domino intramolecular ring-closing metathesis/cross-metathesis reaction to provide styryllactone.

引用

页数：11

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