Monomers for Adhesive Polymers, 10-Synthesis, Radical Photopolymerization and Adhesive Properties of Methacrylates Bearing Phosphonic Acid Groups

被引：10

作者：

Catel, Yohann ^{[1
]}

Fischer, Urs Karl ^{[1
]}

Moszner, Norbert ^{[1
]}

机构：

[1] Ivoclar Vivadent AG, FL-9494 Schaan, Liechtenstein

来源：

MACROMOLECULAR MATERIALS AND ENGINEERING | 2013年 / 298卷 / 07期

关键词：

adhesives; dental polymers; phosphonic acid; photopolymerization; synthesis; POLYMERIZATION; EFFICACY;

D O I：

10.1002/mame.201200196

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Syntheses of eight novel methacrylates bearing phosphonic acid groups were synthesized in three to five steps. The interaction of these monomers with hydroxyapatite was investigated using C-13-NMR spectroscopy. Free radical homopolymerizations were carried out in a mixture ethanol/water (2.5/1, v/v) using 2,2azo(2-methylpropionamidine) dihydrochloride as initiator. The copolymerization of these monomers with a mixture HEMA/GDMA (5/3, mol/mol) was investigated by photo-DSC. Dentin shear bond strength measurements showed that 2-methacryloyloxy-3-(1,1,2,2-tetrafluoroethoxy)propylphosphonic acid 4b, 2,3-dimethacryloyloxypropylphosphonic acid 18 and 3-(methacryloyloxy)-2,2-(di[(dihydroxyphosphoryl)methyl])propyl methacrylate 23 are promising candidates for dental adhesives.

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页码：740 / 756

页数：17

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