Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties

被引:242
作者
Budarin, Vitaly
Clark, James H. [1 ]
Hardy, Jeffrey J. E.
Luque, Rafael
Milkowski, Krzysztof
Tavener, Stewart J.
Wilson, Ashley J.
机构
[1] Univ York, Dept Chem, Clean Technol Ctr, York YO10 5DD, N Yorkshire, England
[2] Royal Soc Chem, London W1J 0BA, England
基金
英国工程与自然科学研究理事会;
关键词
carbohydrates; carbon; mesoporous materials; surface chemistry; thermochemistry;
D O I
10.1002/anie.200600460
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A star is born: The complex molecular architecture found in plants is used in the design of new nanostructured materials. Carbon-based mesoporous materials with tunable surfaces and bulk properties can be synthesized by the low-temperature carbonization of expanded natural starches that are in turn prepared by a simple gelatinization-retrogradation process. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3782 / 3786
页数:5
相关论文
共 49 条
[1]   Amination of activated carbon and adsorption characteristics of its aminated surface [J].
Abe, M ;
Kawashima, K ;
Kozawa, K ;
Sakai, H ;
Kaneko, K .
LANGMUIR, 2000, 16 (11) :5059-5063
[2]   Surface chemical modification of waxy maize starch nanocrystals [J].
Angellier, H ;
Molina-Boisseau, S ;
Belgacem, MN ;
Dufresne, A .
LANGMUIR, 2005, 21 (06) :2425-2433
[3]   An experimentally-based predictive model for the separation of amylopectin subunits during starch gelatinization [J].
Atkin, NJ ;
Abeysekera, RM ;
Cheng, SL ;
Robards, AW .
CARBOHYDRATE POLYMERS, 1998, 36 (2-3) :173-192
[4]   The events leading to the formation of ghost remnants from the starch granule surface and the contribution of the granule surface to the gelatinization endotherm [J].
Atkin, NJ ;
Abeysekera, RM ;
Robards, AW .
CARBOHYDRATE POLYMERS, 1998, 36 (2-3) :193-204
[5]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[6]   Delicious not siliceous: expanded carbohydrates as renewable separation media for column chromatography [J].
Budarin, V ;
Clark, JH ;
Deswarte, FEI ;
Hardy, JJE ;
Hunt, AJ ;
Kerton, FM .
CHEMICAL COMMUNICATIONS, 2005, (23) :2903-2905
[7]   Chemical reactions of double bonds in activated carbon: microwave and bromination methods [J].
Budarin, VL ;
Clark, JH ;
Tavener, SJ ;
Wilson, K .
CHEMICAL COMMUNICATIONS, 2004, (23) :2736-2737
[8]   Surface energy and surface area measurements by 19F MAS NMR of adsorbed trifluoroacetic acid [J].
Budarin, VL ;
Clark, JH ;
Tavener, SJ .
CHEMICAL COMMUNICATIONS, 2004, (05) :524-525
[9]  
BUDARIN VL, 2004, Patent No. 2004003276
[10]   Biopolymers - The structure of starch [J].
Calvert, P .
NATURE, 1997, 389 (6649) :338-339