Amperometric sensing of H2O2 and glucose using wet-chemically deposited MnO2 thin films

被引:4
作者
Kondo, Terukazu [1 ]
Matsushima, Yuta [1 ]
Matsuda, Keigo [1 ]
Unuma, Hidero [1 ]
机构
[1] Yamagata Univ, Grad Sch Sci & Engn, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan
关键词
MnO2; Thin films; Sensor; Hydrogen peroxide; Glucose; MULTIWALLED CARBON NANOTUBES; SENSOR; ELECTRODE; OXIDE; NANOPARTICLES;
D O I
10.2109/jcersj2.17268
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Herein, we report that delta-MnO2 thin films wet-chemically deposited on electro-conductive substrates exhibited good sensing abilities toward hydrogen peroxide and glucose without the assistance of immobilized enzymes, as well as the excellent supercapacitic performance described in our previous paper. High-sensitivity values of 380 mA/(M.cm(2)) (H2O2) and 300 mA/(M.cm(2)) (glucose) were attained with low detection limits of 0.7 mu mol/dm(3) (H2O2) and 0.6 mu mol/dm(3) (glucose). The good sensitivities and low detection limits were attributed to the large surface area of accumulated MnO2 nanosheets and their firm adhesion to the substrates. The method presented herein can be used for facile film deposition with good controllability and reproducibility. (C) 2018 The Ceramic Society of Japan. All rights reserved.
引用
收藏
页码:260 / 262
页数:3
相关论文
共 20 条
[1]   Nonenzymatic electrochemical glucose sensor based on MnO2/MWNTs nanocomposite [J].
Chen, Jin ;
Zhang, Wei-De ;
Ye, Jian-Shan .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (09) :1268-1271
[2]   Effect of crystallographic structure of MnO2 on its electrochemical capacitance properties [J].
Devaraj, S. ;
Munichandraiah, N. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (11) :4406-4417
[3]   3D porous CNT/MnO2 composite electrode for high-performance enzymeless glucose detection and supercapacitor application [J].
Guo, Chunyan ;
Li, Hua ;
Zhang, Xuan ;
Huo, Huanhuan ;
Xu, Cailing .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 206 :407-414
[4]   Genetically Engineered Phage-Templated MnO2 Nanowires: Synthesis and Their Application in Electrochemical Glucose Biosensor Operated at Neutral pH Condition [J].
Han, Lei ;
Shao, Changxu ;
Liang, Bo ;
Liu, Aihua .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (22) :13768-13776
[5]   Electrochemical properties of δ- and γ-MnO2 thin films deposited by a chemical bath technique [J].
Kondo, Terukazu ;
Matsushima, Yuta ;
Matsuda, Keigo ;
Unuma, Hidero .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (08) :8001-8005
[6]   Nonenzymatic electrochemical sensing of hydrogen peroxide based on a polyaniline-MnO2 nanofiber-modified glassy carbon electrode [J].
Lee, Jong-Hyeok ;
Hong, Hun-Gi .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (10) :1153-1162
[7]   Rapid and highly sensitive MnOx nanorods array platform for a glucose analysis [J].
Lee, Sang Ha ;
Yang, Jiao ;
Han, You Jeong ;
Cho, Misuk ;
Lee, Youngkwan .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 218 :137-144
[8]   Electrochemical synthesis of mixed-valence manganese/copper hybrid composite using graphene oxide and multi-walled carbon nanotubes for nonenzymatic glucose sensor [J].
Lin, Kuo-Chiang ;
Huang, Lin-Hsiang ;
Chen, Shen-Ming .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2014, 735 :36-42
[9]  
Nakayama M, 2013, ELECTROANAL, V25, P2283
[10]   Detection of hydrogen peroxide vapor by use of manganese(IV) oxide as catalyst for calorimetric gas sensors [J].
Oberlaender, Jan ;
Kirchner, Patrick ;
Boyen, Hans-Gerd ;
Schoening, Michael J. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2014, 211 (06) :1372-1376