Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes

被引：46

作者：

Cornet, Stephanie M. ^{[2
]}

Haeller, L. Jonas L. ^{[3
]}

Sarsfield, Mark J. ^{[4
]}

Collison, David ^{[5
]}

Helliwell, Madeleine ^{[5
]}

May, Iain ^{[1
]}

Kaltsoyannis, Nikolas ^{[3
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87544 USA

[2] Univ Manchester, Ctr Radiochem Res, Sch Chem, Manchester M13 9PL, Lancs, England

[3] UCL, Dept Chem, London WC 1H, England

[4] UK Natl Nucl Lab, Cent Lab, Seascale CA20 1PG, Cumbria, England

[5] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 08期

基金：

英国工程与自然科学研究理事会; 美国能源部;

关键词：

CATION-CATION INTERACTIONS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; NEPTUNYL CHLORIDE; COORDINATION; DISPROPORTIONATION; ABSORPTION; REDUCTION; CHEMISTRY; BOND;

D O I：

10.1039/b818973k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.

引用

页码：917 / 919

页数：3

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