Metal catalysed hydrovinylation

被引：21

作者：

Ma Ceder, Rosa ^{[1
]}

Grabulosa, Arnald ^{[1
]}

Muller, Guillermo ^{[1
]}

Rocamora, Merce ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 06期

关键词：

P-STEREOGENIC MONOPHOSPHINES; CARBON-QUATERNARY CENTERS; RUTHENIUM-HYDRIDE COMPLEX; C-C LINKAGES; ASYMMETRIC HYDROVINYLATION; ENANTIOSELECTIVE HYDROVINYLATION; ALLYLPALLADIUM COMPLEXES; STEREOSELECTIVE-SYNTHESIS; PHOSPHORAMIDITE LIGANDS; CHIRAL PHOSPHORAMIDITE;

D O I：

10.1039/c3cy00084b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An overview of the hydrovinylation reaction catalysed by transition metal organometallic complexes is given. The addition of ethylene to another C=C double bond of vinylarenes, dienes or strained olefins is highlighted as an elegant methodology to generate a new stereogenic centre. In addition, the introduction of a new vinyl group allows further functionalisation. The parameters that control the selectivity of the formal codimerisation reaction and some selected applications are discussed.

引用

页码：1446 / 1464

页数：19

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