Vicinal Tricarbonyl Compounds: Versatile Building Blocks for Natural Product Synthesis

被引：21

作者：

Selter, Lars ^{[1
]}

Zygalski, Lukas ^{[1
]}

Kerste, Eric ^{[1
]}

Koert, Ulrich ^{[1
]}

机构：

[1] Philipps Univ Marburg, Fachbereich Chem, Hans Meerwein Str 4, D-35032 Marburg, Germany

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 01期

关键词：

vicinal tricarbonyl compounds; stereoselective synthesis; natural products; total synthesis; regioselectivity; 1,3-DICARBONYL COMPOUNDS; SELECTIVE OXIDATION; TRIOXO COMPOUNDS; FACILE SYNTHESIS; CHEMISTRY; 2,3-DIKETOESTERS; STREPTOMYCES; AWAJANOMYCIN; TRIKETONE; YLIDES;

D O I：

10.1055/s-0035-1562623

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Due to their high density of functional groups, vicinal tricarbonyl compounds are versatile building blocks for the synthesis of complex target molecules. Methods for their preparation and their use in stereoselective C-C bond formations, as well as for the synthesis of heteroaromatics, are summarised for the period 2006-2016. Several examples for their applications in natural product synthesis (awajanomycin, cladoniamide, wailupemycin) are presented.

引用

页码：17 / 28

页数：12

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