Visible-Light Hypervalent Iodide Carboxylate Photo(trifluoro)methylations and Controlled Radical Polymerization of Fluorinated Alkenes

被引：87

作者：

Asandei, Alexandru D. ^{[1
,2
]}

Adebolu, Olumide I. ^{[1
,2
]}

Simpson, Christopher P. ^{[1
,2
]}

Kim, Joon-Sung ^{[1
,2
]}

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期

基金：

美国国家科学基金会;

关键词：

block copolymers; hypervalent iodine carboxylates; polymerization; trifluoromethylation; vinylidene fluorides; POLYVALENT IODINE; VINYLIDENE FLUORIDE; ACYL HYPOIODITES; TRIFLUOROMETHYLATION; CHEMISTRY; ALKYL; DECOMPOSITION; PEROXIDE; ALCOHOLS;

D O I：

10.1002/anie.201303826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

IFAB-ulous trifluoromethylation: (CX3COO)2I IIIPh (X=F, H) and (CH3COO)3I V(C6H4COO) are introduced as CX 3./CX3I precursors for metal-free, visible-light, radical (trifluoro)(iodo)methylations of alkenes, illustrated by their use as photoinitiators for the controlled radical polymerization of vinylidene fluoride with external (I(CF2)6I) and insitu generated (CF3I) iodine chain transfer agents, and for block copolymer synthesis. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10027 / 10030

页数：4

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