1,3-transposition of primary allylic alcohols: Synthesis of optically active secondary and tertiary allylic alcohols

被引：18
|
作者：
Dorta, RL
Rodriquez, MS
Salazar, JA
Suarez, E
机构：
[1] CSIC,INST PROD NAT & AGROBIOL,LA LAGUNA 38206,TENERIFE,SPAIN
[2] UNIV LA LAGUNA,DEPT QUIM ORGAN,E-38207 LA LAGUNA,TENERIFE,SPAIN
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 26期
关键词：
D O I：
10.1016/S0040-4039(97)00964-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reduction of optically active 2,3-epoxy alcohols, suitably prepared by the Sharpless asymmetric epoxidation of primary allylic alcohols, with the system triphenylphosphine/iodine/imidazole/2,6-lutidine/water, leads in a single step to optically active secondary and tertiary allylic alcohols. (C) 1997 Elsevier Science Ltd.
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页码：4675 / 4678
页数：4
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