Multiferroic perovskite (Pb0.845Sm0.08Fe0.035)(Ti0.98Mn0.02)O3 with ferroelectric and weak ferromagnetic properties

被引:13
作者
Craciun, F. [1 ]
Dimitriu, E. [2 ]
Grigoras, M. [3 ]
Lupu, N. [3 ]
机构
[1] CNR, ISC, Area Ric Roma Tor Vergata, I-00133 Rome, Italy
[2] REGO COM Srl, Bucharest 050716 5, Romania
[3] Natl Inst Res & Dev Tech Phys, Iasi 700050, Romania
关键词
Ferroelectric materials - Ferromagnetism - Iron compounds - Magnetization - Ferroelectricity - Temperature distribution - Lead titanate - Perovskite - Permittivity - Samarium compounds;
D O I
10.1063/1.4811258
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have investigated the multiferroic properties of PbTiO3 substituted on the A-site with Sm3+ and Fe2+ magnetic ions. We show that the ceramic material with composition (Pb0.845Sm0.08 Fe-0.035)(Ti0.98Mn0.02)O-3 has a spontaneous ferroelectric polarization of about 14 mu C/cm(2) and weak ferromagnetism (remanent magnetization similar to 2.3 emu/g) which persists even at room temperature. The dielectric constant is 190, tan delta similar to 0.005, and the piezoelectric g(33) constant is 25mV x m/N. Temperature dependence of dielectric permittivity shows a strong anomaly at 662 K, at the paraelectric-ferroelectric transition, and a broader anomaly below 140K where magnetization also increases, probably due to magnetoelectric coupling between ferroelectric and magnetic states. (C) 2013 AIP Publishing LLC.
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页数:5
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