Removal of Remazol Black B Textile Dye from Aqueous Solution by Adsorption: Equilibrium and Thermodynamic Studies

被引:11
作者
Bayrak, Yuksel [1 ]
Uzgor, Resmiye [1 ]
机构
[1] Trakya Univ, Dept Chem, Fac Sci, Edirne, Turkey
关键词
Activated carbon; adsorption; orange peel; remazol black B; thermodynamic; REACTIVE DYES; BIOSORPTION; BEHAVIOR; ISOTHERM; KINETICS;
D O I
10.1080/01932691.2012.704749
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of low-cost, easy obtained, high-efficiency, and eco-friendly adsorbents has been investigated as an ideal alternative to the current expensive methods of removing dyes from aqueous solution. This study investigates the potential use of activated carbon prepared from orange peel for the removal of Remazol Black B (RB) dye from aqueous solution. It was seen that the removal of RB increased with increasing solution pH (4-10), solution temperature (25-55 degrees C) and adsorbent dose (0.1-1g/20mL). The maximum dye removal was reached at 90 minutes. Adsorption isotherms were analyzed by Langmuir and Freundlich models at different temperatures of 25 degrees C, 35 degrees C, 45 degrees C, and 55 degrees C, and the results were discussed in detail. Moreover, the thermodynamics of adsorption were also studied. It was found that the values of standard free energy (G degrees) were negative for activated carbon. The values of standard enthalpy (H degrees) and entropy (S degrees) were found to be positive, and the obtained results were interpreted in detail. Activated carbon developed from orange peel can be attractive options for dye removal from diluted industrial effluents since test reaction made on simulated dyeing aqueous solution show better removal percentage of RB.
引用
收藏
页码:828 / 833
页数:6
相关论文
共 23 条
[1]  
Acemioglu B, 2004, FRESEN ENVIRON BULL, V13, P585
[2]   Removal of Fe(II) ions from aqueous solution by Calabrian pine bark wastes [J].
Acemioglu, B .
BIORESOURCE TECHNOLOGY, 2004, 93 (01) :99-102
[3]   Comparison of Remazol Black B biosorptive properties of live and treated activated sludge [J].
Aksu, Zumriye ;
Akin, Ahmet Burak .
CHEMICAL ENGINEERING JOURNAL, 2010, 165 (01) :184-193
[4]   Effect of carbon surface chemistry on the removal of reactive dyes from textile effluent [J].
Al-Degs, Y ;
Khraisheh, MAM ;
Allen, SJ ;
Ahmad, MN .
WATER RESEARCH, 2000, 34 (03) :927-935
[5]   Adsorption characteristics of reactive dyes in columns of activated carbon [J].
Al-Degs, Y. S. ;
Khraisheh, M. A. M. ;
Allen, S. J. ;
Ahmad, M. N. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 165 (1-3) :944-949
[6]   Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon [J].
Al-Degs, Yahya S. ;
El-Barghouthi, Musa I. ;
El-Sheikh, Amjad H. ;
Walker, Gavin M. .
DYES AND PIGMENTS, 2008, 77 (01) :16-23
[7]  
Alvin W. M., 2010, CHEM ENG J, V157, P434
[8]   Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis [J].
Annadurai, Gurusamy ;
Ling, Lai Yi ;
Lee, Jiunn-Fwu .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (01) :337-346
[9]   Modified hectorites and adsorption studies of a reactive dye [J].
Baskaralingam, P. ;
Pulikesi, M. ;
Ramamurthi, V. ;
Sivanesan, S. .
APPLIED CLAY SCIENCE, 2007, 37 (1-2) :207-214
[10]   Adsorption behavior of Cr(VI) on activated hazelnut shell ash and activated bentonite [J].
Bayrak, Y ;
Yesiloglu, Y ;
Gecgel, U .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 91 (1-3) :107-110