Hydrogenation of Chlorosilanes by NaBH4

被引：13

作者：

Ito, Masaki ^{[1
]}

Itazaki, Masumi ^{[1
]}

Abe, Takashi ^{[2
]}

Nakazawa, Hiroshi ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan

[2] Nippon Shokubai Co Ltd, Adv Mat Res Ctr, 5-8 Nishi Otabi Cho, Suita, Osaka 5648512, Japan

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 12期

关键词：

Hydrogenation; Chlorosilane; NaBH4; RHODIUM-CATALYZED REDUCTION; C-F ACTIVATION; SELECTIVE REDUCTION; CHEMOSELECTIVE REDUCTION; TERTIARY AMIDES; CARBON-DIOXIDE; HYDROSILYLATION; ALDEHYDES; ESTERS; KETONES;

D O I：

10.1246/cl.160808

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of chlorosilane was achieved in acetonitrile using NaBH4, a safe and easy-to-handle reagent. This reaction converted Si-Cl portion(s) in organosilanes into Si-H portion(s) without hydrogenation of cyano, chloro, and aldehyde groups on an alkyl substituent of the Si reagents. In addition, the Si-Cl/Si-H exchange reaction was applicable to dichlorodisilane without Si-Si bond cleavage.

引用

页码：1434 / 1436

页数：3

共 50 条

[21] Native Defects and the Dehydrogenation of NaBH4
Cakir, Deniz
de Wijs, Gilles A.
Brocks, Geert
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (49): : 24429 - 24434
[22] Hydrogen generation by hydrolysis of NaBH4
Cento, C.
Gislon, P.
Prosini, P. P.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (10) : 4551 - 4554
[23] Controllable hydrogenation of arylacetylenes with NaBH4 catalyzed by palladium nanoparticles in a fixed-bed system
Zhang, Wei
Wu, Guohao
Wang, Ying
Zhang, Yanhua
TETRAHEDRON LETTERS, 2024, 152
[24] Suitability of cyclic voltammetry for the measurement of sodium borohydride (NaBH4) in a solution of Cr(VI)/organic compounds/NaBH4
Njoya, Ousmanou
Pam, Seidou
Oyono, Joseph Sadrack Ondoua
WATER PRACTICE AND TECHNOLOGY, 2024, 19 (07) : 2920 - 2928
[25] Reorientational Dynamics of NaBH4 and KBH4
Verdal, Nina
Hartman, Michael R.
Jenkins, Timothy
DeVries, Daniel J.
Rush, John J.
Udovic, Terrence J.
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (21): : 10027 - 10033
[26] Fast and Efficient Reductive Amination of Aldehydes by NaBH4/B(OH)3 and NaBH4/Al(OH)3
Setamdideh, Davood
Hasani, Samira
Noori, Shahla
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2013, 60 (10) : 1267 - 1271
[27] Explaining LiAlH4, NaBH4 reactivities
不详
CHEMICAL & ENGINEERING NEWS, 2005, 83 (35) : 27 - 27
[28] Production of NaBH4 and hydrogen release with catalyst
Cakanyildirim, Cetin
Guru, Metin
RENEWABLE ENERGY, 2009, 34 (11) : 2362 - 2365
[29] Destabilization of NaBH4 by Transition Metal Fluorides
Jansa, Isabel Llamas
Kalantzopoulos, Georgios N.
Nordholm, Kari
Hauback, Bjorn C.
MOLECULES, 2020, 25 (04):
[30] THE ACTION OF NABH4 ON NAHSO3
PANSON, GS
WEILL, CE
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1960, 15 (1-2): : 184 - 185

← 1 2 3 4 5 →