Hydrogenation of Chlorosilanes by NaBH4

被引：13

作者：

Ito, Masaki ^{[1
]}

Itazaki, Masumi ^{[1
]}

Abe, Takashi ^{[2
]}

Nakazawa, Hiroshi ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan

[2] Nippon Shokubai Co Ltd, Adv Mat Res Ctr, 5-8 Nishi Otabi Cho, Suita, Osaka 5648512, Japan

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 12期

关键词：

Hydrogenation; Chlorosilane; NaBH4; RHODIUM-CATALYZED REDUCTION; C-F ACTIVATION; SELECTIVE REDUCTION; CHEMOSELECTIVE REDUCTION; TERTIARY AMIDES; CARBON-DIOXIDE; HYDROSILYLATION; ALDEHYDES; ESTERS; KETONES;

D O I：

10.1246/cl.160808

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of chlorosilane was achieved in acetonitrile using NaBH4, a safe and easy-to-handle reagent. This reaction converted Si-Cl portion(s) in organosilanes into Si-H portion(s) without hydrogenation of cyano, chloro, and aldehyde groups on an alkyl substituent of the Si reagents. In addition, the Si-Cl/Si-H exchange reaction was applicable to dichlorodisilane without Si-Si bond cleavage.

引用

页码：1434 / 1436

页数：3

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